Magnesium-catalyzed synthesis of organic carbonate from 1,2-diol/alcohol and carbon dioxide

被引：64
|
作者：
Du, Ya [1 ,2 ]
He, Liang-Nian [1 ,2 ]
Kong, De-Lin [1 ,2 ]
机构：
[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 08期
基金：
中国国家自然科学基金;
关键词：
carbonylation; propylene glycol; propylene carbonate; magnesium; carbon dioxide;
D O I：
10.1016/j.catcom.2008.02.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Low toxic magnesium and its oxide are proved to be a catalyst for highly selective synthesis of propylene carbonate (PC) through the carbonylation of propylene glycol (PG) with CO2 without any organic solvents or additives. Interestingly, the catalyst was demonstrated to be applicable to a variety of 1,2-diols such as glycol, phenyl glycol, and methanol, forming the corresponding carbonates in 100% selectivity. As a result, employing a low toxic and cheap catalyst could make PC synthesis much environmentally friendlier. A mechanistic insight into the Sn/Mg-catalyzed reaction of "PG + CO2" was also studied herein. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1754 / 1758
页数：5
相关论文
共 50 条
  • [1] Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters
    Cao, Xu
    Wang, Weifan
    Lu, Kai
    Yao, Weiwei
    Xue, Fei
    Ma, Mengtao
    DALTON TRANSACTIONS, 2020, 49 (09) : 2776 - 2780
  • [2] DIRECT SYNTHESIS OF MONOCARBAMIC ESTER OF 1,2-DIOL FROM CARBON-DIOXIDE, EPOXIDE AND AMINE
    YOSHIDA, Y
    INOUE, S
    CHEMISTRY LETTERS, 1978, (02) : 139 - 140
  • [3] Homogeneous and silica-supported zinc complexes for the synthesis of propylene carbonate from propane-1,2-diol and carbon dioxide
    Comerford, James W.
    Hart, Sam J.
    North, Michael
    Whitwood, Adrian C.
    CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (13) : 4824 - 4831
  • [4] Alcohol and 1,2-diol dehydrogenases: Synthetic use as oxidants
    Sello, G
    Orsini, F
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2006, 3 (01) : 11 - 21
  • [5] New synthesis of 1,2-diol monopropargyl ethers
    G. M. Talybov
    Russian Journal of Organic Chemistry, 2017, 53 : 123 - 124
  • [6] New Synthesis of 1,2-Diol Monopropargyl Ethers
    Talybov, G. M.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 53 (01) : 123 - 124
  • [7] INVESTIGATION OF PLUTONIUM CHLORO SPECIES IN PROPANE 1,2-DIOL CARBONATE
    BRYAN, GH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1969, (SEP): : NU58 - &
  • [8] Lipase-catalyzed enantio selective acylation of 3-benzyloxypropane-1,2-diol in supercritical carbon dioxide
    Kmecz, I
    Simándi, B
    Poppe, L
    Juvancz, Z
    Renner, K
    Bódai, V
    Toke, ER
    Csajági, C
    Sawinsky, J
    BIOCHEMICAL ENGINEERING JOURNAL, 2006, 28 (03) : 275 - 280
  • [9] Synthesis of propylene carbonate from carbon dioxide and 1,2-propylene glycol with organic base catalyst
    State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
    不详
    不详
    Shiyou Huagong, 2007, 6 (601-604):
  • [10] LIPASE-CATALYZED ENANTIOMER SELECTIVE HYDROLYSIS OF 1,2-DIOL DIACETATES
    POPPE, L
    NOVAK, L
    KAJTARPEREDY, M
    SZANTAY, C
    TETRAHEDRON-ASYMMETRY, 1993, 4 (10) : 2211 - 2217
12345