A molecular structure of bis(N-octylethylenediamine)zinc(II) nitrate in crystal and the aggregations in wet chloroform and benzene solutions

被引：15

作者：

Iida, M ^{[1
]}

Tanase, T ^{[1
]}

Asaoka, N ^{[1
]}

Nakanishi, A ^{[1
]}

机构：

[1] Nara Womens Univ, Fac Sci, Dept Chem, Nara 6308506, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 12期

关键词：

D O I：

10.1246/cl.1998.1275

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc complex with N-octylethylenediamine(= OE), Zn(OE)(2)(NO3)(2), was prepared and its molecular structure was determined on the basis of an X-ray crystallographic analysis. It was revealed that in the octahedral molecular structure the nitrate groups are trans and the octyl chains are transoid. Extensive aggregations of this complex in wet chloroform and wet benzene systems were also studied using H-1 NMR self-diffusions for the solvents and the zinc complex.

引用

页码：1275 / 1276

页数：2

共 7 条

[1] FT-PGSE NMR study of mixed micellization of an anionic and a sugar-based nonionic surfactant [J].

Griffiths, PC ;

Stilbs, P ;

Paulsen, K ;

Howe, AM ;

Pitt, AR .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (06) :915-918

[2] A novel reverse micellar system composed of bis(octylethylenediamine)zinc(II) chloride in aqueous benzene and chloroform solutions [J].

Iida, M ;

Yonezawa, A ;

Tanaka, J .

CHEMISTRY LETTERS, 1997, (07) :663-664

[3] Hydrophobic control of diastereoselectivity in the synthesis of double-chain surfactant Co(III) complexes [J].

Jaeger, DA ;

Reddy, VB ;

Arulsamy, N ;

Bohle, DS ;

Grainger, DW ;

Berggren, B .

LANGMUIR, 1998, 14 (10) :2589-2592

[4] Complexes of copper(II) carboxylates with ammonia. Crystal structure of Cu(O2CC9H19)(2)(NH3)(2)(H2O) [J].

Petric, M ;

Leban, I ;

Segedin, P .

POLYHEDRON, 1996, 15 (23) :4277-4282

[5] PREPARATION AND CHARACTERIZATION OF COPPER(II) COORDINATION-COMPOUNDS WITH LINEAR-CHAIN FATTY-ACIDS WITH 7-12 CARBON-ATOMS AND PYRIDINE - CRYSTAL-STRUCTURE OF CU(O2CC8H17)(2)(PY)(2)(H2O) [J].

PETRIC, M ;

LEBAN, I ;

SEGEDIN, P .

POLYHEDRON, 1995, 14 (08) :983-989

[6]

Sierra T, 1996, METALLOMESOGENS

[7]

STILBS P, 1986, PROG NUCL MAGN RESON, V19, P1

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