[5-Chloro-2-hydroxy-N'-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV)

被引:0
|
作者
Zhang, Xiuyun [1 ]
Yue, Caihong [1 ]
Yin, Handong [1 ]
机构
[1] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
基金
中国国家自然科学基金;
关键词
data-to-parameter ratio = 14.0; mean σ(CC) = 0.005 Å; R factor = 0.029; single-crystal X-ray study; T = 298 K; wR factor = 0.071;
D O I
10.1107/S1600536811025621
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Sn(CH3)(2)(C14H9ClN2O3)], the Sn-IV ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hydroxy-N'-(2-oxidobenzylidene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal-bipyramidal geometry. In the ligand, the hydroxy group is involved in an intramolecular O-H center dot center dot center dot N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5 (1)degrees. In the crystal, weak intermolecular C-H center dot center dot center dot O hydrogen bonds and pi-pi interactions between the aromatic rings [centroid- centroid distance = 3.816 (3) angstrom] link the molecules into centrosymmetric dimers.
引用
收藏
页码:M1028 / U301
页数:10
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