Volumetric properties of binary mixtures of {difluoromethane (R32) + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} at temperatures from 283.15 K to 363.15 K and pressures up to 100 MPa

被引:27
|
作者
Jia, Tao [1 ]
Bi, Shengshan [1 ]
Hu, Xiaozhen [1 ]
Meng, Xianyang [1 ]
Wu, Jiangtao [1 ]
机构
[1] Xi An Jiao Tong Univ, Key Lab Thermofluid Sci & Engn, Minist Educ, Sch Energy & Power Engn, Xian 710049, Peoples R China
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2016年 / 101卷
基金
中国国家自然科学基金;
关键词
R32; R1234ze(E); Density; Excess molar volume; Vibrating-tube densimeter; EXCESS MOLAR VOLUMES; LIQUID DENSITY; 100; MPA; THERMODYNAMIC PROPERTIES; PENTAFLUOROETHANE R125; DIFLUOROMETHANE R32; 298.15; K; PRESSURES; TEMPERATURES; TRANS-1,3,3,3-TETRAFLUOROPROPENE;
D O I
10.1016/j.jct.2016.05.013
中图分类号
O414.1 [热力学];
学科分类号
摘要
Values of experimental density of difluoromethane (R32) and five compositions of {R32 + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} binary mixtures are reported over the temperature range from 283 K to 363 K and at pressures up to 100 MPa with a vibrating-tube densimeter. The excess molar volumes were calculated from experimental results and fitted to the Redlich-Kister equation. The maximum standard deviation and average standard deviations of the experimental and calculated values of excess molar volume from Redlich-Kister equation are 0.07789 cm(3).mol(-1) and 0.01645 cm(3).mol(-1), respectively. (C) 2016 Published by Elsevier Ltd.
引用
收藏
页码:54 / 63
页数:10
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