Crystal structure of tris-(dipivaloylmethanato) (ethylendiamine)yttrium(III)

被引：0
作者：
Mosyagina, S. A. [1 ,2 ]
Kuratieva, N. V. [1 ,2 ]
Zherikova, K. V. [2 ]
机构：
[1] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 08期
基金：
俄罗斯科学基金会;
关键词：
yttrium; dipivaloylmethane; ethylendiamine; synthesis; single crystal X-ray diffraction analysis; THIN-FILMS; PRECURSORS; HEXAFLUOROACETYLACETONATE; DEPOSITION; LIGAND; MOCVD; ZR;
D O I：
10.1134/S0022476617080108
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of a mixed-ligand complex tris-(dipivaloylmethanato)(ethylendiamine)yttrium(III) [Y(en)(dpm)(3)] is studied at 150(2) K by single crystal XRD. The crystallographic data for C35H65N2O6Y are as follows: space group P2(1)/c, a = 10.3771(3) , b = 26.3566(8) , c = 14.8412(4) , beta = 100.385(2)A degrees, V = 3992.6(2) (3), Z = 4. The structure is molecular. The coordination environment of yttrium atoms is square antiprismatic; the Y-D distances are 2.2597(13)-2.3760(12) and Y-N distances are 2.5381(16) and 2.5499(17) .
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页码：1546 / 1550
页数：5
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