One-pot synthesis of bicyclic polystyrene by combination of ATRP and click chemistry

被引:5
|
作者
Choi, Hyerin [1 ]
Lee, Taeheon [1 ]
Jeong, Jonghwa [1 ]
Ye, Jihwa [1 ]
Jeon, Heung Bae [2 ]
Paik, Hyun-jong [1 ]
机构
[1] Pusan Natl Univ, Dept Polymer Sci & Engn, Busan 46241, South Korea
[2] Kwangwoon Univ, Dept Chem, Seoul 01897, South Korea
关键词
atom transfer radical polymerization; click chemistry; one-pot synthesis; macrocyclization; bicyclic polymer; TRANSFER RADICAL POLYMERIZATION; CYCLIC POLYMERS; STAR POLYMERS; COPOLYMERS; STRATEGIES; BRUSHES;
D O I
10.1007/s13233-016-4119-0
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A series of bicyclic polystyrenes of different molecular weights was synthesized in one-pot by atom transfer radical polymerization followed by click chemistry. The bicyclic polystyrenes were formed simultaneously with branched polystyrene impurities due to side reactions during click coupling. The pure bicyclic polystyrenes were obtained by selective precipitation. The purity of bicyclic polystyrenes before purification was determined by Gaussian multiple peak fitting from SEC trace. The bicyclic polymers were characterized by SEC, H-1 NMR, and FTIR spectroscopy.
引用
收藏
页码:856 / 861
页数:6
相关论文
共 50 条
  • [1] One-pot synthesis of bicyclic polystyrene by combination of ATRP and click chemistry
    Hyerin Choi
    Taeheon Lee
    Jonghwa Jeong
    Jihwa Ye
    Heung Bae Jeon
    Hyun-jong Paik
    Macromolecular Research, 2016, 24 : 856 - 861
  • [2] Facile route to synthesis of bicyclic polystyrene using ATRP and click chemistry by one-pot
    Ye, Jihwa
    Lee, Taeheon
    Choi, Hyerin
    Jeong, Jonghwa
    Paik, Hyun-Jong
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [3] One-pot synthesis of well-defined amphiphilic and adaptative block copolymers via versatile combination of "Click" chemistry and ATRP
    Mespouille, Laetitia
    Vachaudez, Magali
    Suriano, Fabian
    Gerbaux, Pascal
    Coulembier, Olivier
    Degee, Philippe
    Flammang, Robert
    Dubois, Philippe
    MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (22) : 2151 - 2158
  • [4] One-Pot Synthesis of ABC Miktoarm Star Terpolymers by Coupling ATRP, ROP, and Click Chemistry Techniques
    Zhang, Yanfeng
    Li, Changhua
    Liu, Shiyong
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (12) : 3066 - 3077
  • [5] Synthesis of Well-Defined Telechelic Macrophotoinitiator of Polystyrene by Combination of ATRP and Click Chemistry
    Degirmenci, Mustafa
    Genli, Nasrettin
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (19) : 1617 - 1623
  • [6] Functionalized Random Copolymers from Versatile One-Pot Click Chemistry/ATRP Tandems Approaches
    Damiron, Denis
    Desorme, Mylene
    Ostaci, Roxana-Viorela
    Al Akhrass, Samer
    Hamaide, Thierry
    Drockenmuller, Eric
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (15) : 3803 - 3813
  • [7] One-Pot Synthesis of Brush Diblock Copolymers through Simultaneous ATRP and Click Coupling
    Han, Dehui
    Tong, Xia
    Zhao, Yue
    MACROMOLECULES, 2011, 44 (13) : 5531 - 5536
  • [8] A multicomponent polymerization system: click-chemoenzymatic-ATRP in one-pot for polymer synthesis
    Zhang, Yun
    Fu, Changkui
    Zhu, Chongyu
    Wang, Shiqi
    Tao, Lei
    Wei, Yen
    POLYMER CHEMISTRY, 2013, 4 (03) : 466 - 469
  • [9] One-pot peptide and protein conjugation: a combination of enzymatic transamidation and click chemistry
    Rachel, N. M.
    Pelletier, J. N.
    CHEMICAL COMMUNICATIONS, 2016, 52 (12) : 2541 - 2544
  • [10] Surface modification of polysulfones via one-pot ATRP and click chemistry: Zwitterionic graft complex and their hemocompatibility
    Shaojin Gu
    Huan Xia
    Jiehao Du
    Ling Yang
    Yajun Cai
    Yingshan Zhou
    Jingjing Huang
    Fibers and Polymers, 2016, 17 : 161 - 165