Synthesis, characterization, and intervalence charge transfer properties of a series of rhenium(I)-iron(III) mixed-valence compounds

被引：28
|
作者：
Pfennig, BW
Cohen, JL
Sosnowski, I
Novotny, NM
Ho, DM
机构：
[1] Vassar Coll, Dept Chem, Poughkeepsie, NY 12604 USA
[2] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
来源：
INORGANIC CHEMISTRY | 1999年 / 38卷 / 03期
关键词：
D O I：
10.1021/ic9811751
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of cyanide-bridged mixed-valence compounds of the form {[dmbRe(I)(CO)(3)](n)-Fe-III(CN)(6)}(3-n) were synthesized, and their MM'CT absorptions were modeled using Marcus-Hush theory. The hypsochromic shift of the MM'CT bands with increasing it is due to the increase in the redox potential of the Fe(III) center as more Re(I) species are bridged to it. The single-crystal X-ray structure of the 3:1 (Re/Fe) species was also determined, and a solvent dependence was performed.
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页码：606 / +
页数：8
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