MnIII-Salen composite materials based on Keggin heteropolyanions exhibiting photocatalytic and electrocatalytic activities

被引：10

作者：

Meng, Xing ^{[1
]}

Wang, Hai-Ning ^{[1
]}

Yang, Guang-Sheng ^{[1
]}

Wang, Shuang ^{[1
]}

Wang, Xin-Long ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

Su, Zhong-Min ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Key Lab Polyoxometalate Sci, Inst Funct Mat Chem,Minist Educ, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 09期

基金：

中央高校基本科研业务费专项资金资助;

关键词：

Inorganic-organic hybrid material; Metal-Schiff-base; Keggin polyanions; Catalytic activity; POLYOXOMETALATE HYBRID COMPOUND; SCHIFF-BASE; CATALYTIC-OXIDATION; METAL-COMPLEXES; CLUSTERS; ELECTROCHEMISTRY; NANOSTRUCTURES; REDUCTION; ELECTRODE;

D O I：

10.1016/j.inoche.2011.05.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new inorganic-organic hybrid supramolecular compounds based on Keggin-type polyoxoanions, namely [Mn(salen)(CH3OH)(2)](3)[PMo12O40] (1) and [Mn(salen)(CH3OH)(2)](3)[PW12O40](2) (H(2)salen = N,N'-ethylenebis (salicylideneimine)) have been synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectroscopy, and TG analysis. Two compounds reported herein represent the first examples of integrating metal-Schiff-base segments with Keggin polyanions characterized via single-crystal X-ray diffraction. Such hybrid materials display photocatalytic and electrocatalytic bifunctional catalytic activities. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.

引用

页码：1418 / 1421

页数：4

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