Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)-phenol-κN3]bis(nitrato-κO)copper(II)

被引：2
|
作者：
Yu, Rui-Jin [1 ]
Deng, Bin [2 ]
机构：
[1] NW A& F Univ, Coll Sci, Yangling 712100, Shaanxi, Peoples R China
[2] Xiangnan Univ, Dept Chem & Life & Sci, Chenzhou 423000, Hunan, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
CRYSTAL-STRUCTURES; HYDROGENCYANAMIDE; CARBODIIMIDE; CYANAMIDE;
D O I：
10.1107/S1600536811032399
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A pair of linear cyanamide (NCNH2) ligands, two monodentate 4-(1H-imidazol-1-yl) phenol (L) ligands and two nitrate anions link the Cu-II atom into a mononuclear unit, [Cu(NO3)(2)(C9H8N2O)(2)(NCNH2)(2)]. The coordination polyhedron of the Cu atom is an elongated octahedron distorted by Jahn-Teller effects. Intermolecular O-H center dot center dot center dot O, O-H center dot center dot center dot N, N-H center dot center dot center dot O and N-H center dot center dot center dot N hydrogen-bonding interactions link these units into a three-dimensional supramolecular architecture.
引用
收藏
页码：M1253 / U897
页数：9
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