Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)-phenol-κN3]bis(nitrato-κO)copper(II)

被引:2
作者
Yu, Rui-Jin [1 ]
Deng, Bin [2 ]
机构
[1] NW A& F Univ, Coll Sci, Yangling 712100, Shaanxi, Peoples R China
[2] Xiangnan Univ, Dept Chem & Life & Sci, Chenzhou 423000, Hunan, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
CRYSTAL-STRUCTURES; HYDROGENCYANAMIDE; CARBODIIMIDE; CYANAMIDE;
D O I
10.1107/S1600536811032399
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A pair of linear cyanamide (NCNH2) ligands, two monodentate 4-(1H-imidazol-1-yl) phenol (L) ligands and two nitrate anions link the Cu-II atom into a mononuclear unit, [Cu(NO3)(2)(C9H8N2O)(2)(NCNH2)(2)]. The coordination polyhedron of the Cu atom is an elongated octahedron distorted by Jahn-Teller effects. Intermolecular O-H center dot center dot center dot O, O-H center dot center dot center dot N, N-H center dot center dot center dot O and N-H center dot center dot center dot N hydrogen-bonding interactions link these units into a three-dimensional supramolecular architecture.
引用
收藏
页码:M1253 / U897
页数:9
相关论文
共 16 条
  • [1] Becker M, 2000, Z ANORG ALLG CHEM, V626, P2505, DOI 10.1002/1521-3749(200012)626:12<2505::AID-ZAAC2505>3.0.CO
  • [2] 2-#
  • [3] SYNTHESES, CRYSTAL-STRUCTURES, AND VIBRATIONAL SPECTROSCOPIC PROPERTIES OF MGCN2, SRCN2, AND BACN2
    BERGER, U
    SCHNICK, W
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 206 (02) : 179 - 184
  • [4] *BRUK AXS INC, 1998, SMART
  • [5] Bruker, 1999, SAINT PLUS
  • [6] AN UNUSUAL CUII-PROMOTED DESULFURIZATION OF THIOUREA - SYNTHESIS AND CRYSTAL-STRUCTURE OF DI-MU-HYDROGENCYANAMIDO(1-)-BIS[(N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)COPPER(II)] DI-PERCHLORATE MONOHYDRATE
    CHAUDHURI, P
    WIEGHARDT, K
    NUBER, B
    WEISS, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (05) : 265 - 266
  • [7] A ROOM-TEMPERATURE ORGANOMETALLIC MAGNET BASED ON PRUSSIAN BLUE
    FERLAY, S
    MALLAH, T
    OUAHES, R
    VEILLET, P
    VERDAGUER, M
    [J]. NATURE, 1995, 378 (6558) : 701 - 703
  • [8] Crystal structures of extended europium cyanamide-carbodiimide compounds derived from different reaction conditions:: Temperature-controlled syntheses of In0.08Eu4(NCN)3I3, Eu8I9(CN)(NCN)3, and In0.28Eu12(NCN)5I14.91
    Liao, Wuping
    Dronskowski, Richard
    [J]. INORGANIC CHEMISTRY, 2006, 45 (10) : 3828 - 3830
  • [9] Synthesis, crystal structure, and properties of MnNCN, the first carbodiimide of a magnetic transition metal
    Liu, XH
    Krott, M
    Muller, P
    Hu, CH
    Lueken, H
    Dronskowski, R
    [J]. INORGANIC CHEMISTRY, 2005, 44 (09) : 3001 - 3003
  • [10] Meyer F, 2000, EUR J INORG CHEM, P771