Kopsihainanines A and B, two unusual alkaloids from Kopsia hainanensis

被引:46
作者
Chen, Jia [1 ]
Chen, Jian-Jun [1 ]
Yao, Xiaojun [1 ]
Gao, Kun [1 ]
机构
[1] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
INDOLE ALKALOIDS; LEAVES;
D O I
10.1039/c1ob05724c
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Kopsihainanine A (1), an unprecedented skeleton with a 6/5/6/6/6 pentacyclic rearranged ring system, together with a new biogenetically related compound, kopsihainanine B (2), were isolated from Kopsia hainanensis. Their structures were elucidated by means of spectroscopic methods. The absolute configuration of 1 was determined by ECD calculation.
引用
收藏
页码:5334 / 5336
页数:3
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