Improved Na Storage Performance with the Involvement of Nitrogen-Doped Conductive Carbon into WS2 Nanosheets

被引:72
作者
Wang, Xin [1 ]
Huang, Jianfeng [1 ]
Li, Jiayin [1 ]
Cao, Liyun [1 ]
Hao, Wei [2 ]
Xu, Zhanwei [1 ]
机构
[1] Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Xian 710021, Shaanxi, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
关键词
tungsten disulfide; nitrogen-doped conductive carbon; electronic conductivity; electrochemical performance; sodium ion batteries; REDUCED GRAPHENE OXIDE; LITHIUM ION BATTERIES; ELECTROCHEMICAL PROPERTIES; ANODE PERFORMANCE; SODIUM; NANOFIBERS; MICROSPHERES; BINDER;
D O I
10.1021/acsami.6b06032
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Tungsten disulfide (WS2) material is regarded as One of the most promising anode candidates for sodium ion batteries,(SIBs). However, the exploration of this material still remains a great Challenge to improve its cycling capacity. In this paper, nitrogen-doped conductive carbon/WS2 nanocomposites (WS2-NC) were fabricated based on the synthesis of the pure WS2, and conductive carbon/WS2 (WS2-C) nanocomposites. The reversible capacity of the as-prepared WS2-NC is stabilized at similar to 360 mA h g(-1). at the density of 100 mA g(-1), even similar to 200 mA h g(-1) at 1 A g(-1), presenting much better cycling performance than pure WS2 and conductive carbon/WS2 (WS2-C) samples. This excellent performance is further attributed to obviously promoted interfacial reaction in WS2 nanosheets at a low voltage platform (03-0.0 V), which is considered to closely relate to the incorporation of nitrogen-doped conductive carbon into WS2 nanosheets. Generally; this work presents an,obviously enhanced Na storage performance by the incorporation of N-doped carbon into WS2 nanosheets to promote their interfacial reaction at low voltage platform. It could provide guidelines to create other-high-capacity anode sulfide materials for SIBs.,
引用
收藏
页码:23899 / 23908
页数:10
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