Using hard X-ray photoelectron spectroscopy to study a SiO2/HfO2-based interface dipole modulation stack embedded in a metal-insulator-metal structure

被引:8
作者
Kirihara, Yoshiharu [1 ]
Tsujiguchi, Ryota [1 ]
Ito, Shunichi [1 ]
Yasui, Akira [2 ]
Miyata, Noriyuki [3 ]
Nohira, Hiroshi [1 ]
机构
[1] Tokyo City Univ, Setagaya Ku, Tokyo 1588557, Japan
[2] Japan Synchrotron Radiat Res Inst JASRI, Sayo, Hyogo 6795198, Japan
[3] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058568, Japan
关键词
hard X-ray photoelectron spectroscopy; metal-insulator-metal structure; interface dipole modulation; change in the chemical bonding state of Ti;
D O I
10.35848/1882-0786/ac9ae6
中图分类号
O59 [应用物理学];
学科分类号
摘要
Hard X-ray photoelectron spectroscopy was used to examine the interface dipole modulation of SiO2/1-monolayer titanium oxide/HfO2 stack embedded in a metal-insulator-metal structure. Reversible shifts in the Si 1 s, Hf 3d, and Ti 1 s photoelectron peaks were induced by electrical stress, and they indicate the switching of the potential profile inside the SiO2/titanium oxide/HfO2 stack. Moreover, a proportion change in the Ti3+ component correlates with the potential switching, and that correlation suggests that the structural change around the interface titanium atoms leads to the interface dipole modulation.
引用
收藏
页数:5
相关论文
共 30 条
[1]   Effect of Oxide Charge Trapping on X-ray Photoelectron Spectroscopy of HfO2/SiO2/Si Structures [J].
Abe, Yasuhiro ;
Miyata, Noriyuki ;
Ikenaga, Eiji ;
Suzuki, Haruhiko ;
Kitamura, Koji ;
Igarashi, Satoru ;
Nohira, Hiroshi .
JAPANESE JOURNAL OF APPLIED PHYSICS, 2009, 48 (04)
[2]   In-operando and non-destructive analysis of the resistive switching in the Ti/HfO2/TiN-based system by hard x-ray photoelectron spectroscopy [J].
Bertaud, Thomas ;
Sowinska, Malgorzata ;
Walczyk, Damian ;
Thiess, Sebastian ;
Gloskovskii, Andrei ;
Walczyk, Christian ;
Schroeder, Thomas .
APPLIED PHYSICS LETTERS, 2012, 101 (14)
[3]   Improved high-temperature leakage in high-density MIM capacitors by using a TiLaO dielectric and an Ir electrode [J].
Cheng, C. H. ;
Pan, H. C. ;
Yang, H. J. ;
Hsiao, C. N. ;
Chou, C. P. ;
McAlister, S. P. ;
Chin, Albert .
IEEE ELECTRON DEVICE LETTERS, 2007, 28 (12) :1095-1097
[4]   Understanding the role of buried interface charges in a metal-oxide-semiconductor stack of Ti/Al2O3/Si using hard x-ray photoelectron spectroscopy [J].
Church, J. R. ;
Weiland, C. ;
Opila, R. L. .
APPLIED PHYSICS LETTERS, 2015, 106 (17)
[5]   Surface chemistry and optical property of TiO2 thin films treated by low-pressure plasma [J].
Dhayal, Marshal ;
Jun, Jin ;
Gu, Hal Bon ;
Park, Kyung Hee .
JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (10) :2696-2701
[6]  
Fadley C.S., 2016, HARD XRAY PHOTOELECT
[7]   Evaluation of valence band top and electron affinity of SiO2 and Si-based semiconductors using X-ray photoelectron spectroscopy [J].
Fujimura, Nobuyuki ;
Ohta, Akio ;
Makihara, Katsunori ;
Miyazaki, Seiichi .
JAPANESE JOURNAL OF APPLIED PHYSICS, 2016, 55 (08)
[8]   Understanding the limits of ultrathin SiO2 and Si-O-N gate dielectrics for sub50 nm CMOS [J].
Green, ML ;
Sorsch, TW ;
Timp, GL ;
Muller, DA ;
Weir, BE ;
Silverman, PJ ;
Moccio, SV ;
Kim, YO .
MICROELECTRONIC ENGINEERING, 1999, 48 (1-4) :25-30
[9]  
Hashimoto S., 2002, J SURF ANAL, V9, P459, DOI [10.1384/jsa.9.459, DOI 10.1384/JSA.9.459]
[10]   Growth of HfO2/TiO2 nanolaminates by atomic layer deposition and HfO2-TiO2 by atomic partial layer deposition [J].
Hernandez-Arriaga, H. ;
Lopez-Luna, E. ;
Martinez-Guerra, E. ;
Turrubiartes, M. M. ;
Rodriguez, A. G. ;
Vidal, M. A. .
JOURNAL OF APPLIED PHYSICS, 2017, 121 (06)