Using hard X-ray photoelectron spectroscopy to study a SiO2/HfO2-based interface dipole modulation stack embedded in a metal-insulator-metal structure

被引:7
作者
Kirihara, Yoshiharu [1 ]
Tsujiguchi, Ryota [1 ]
Ito, Shunichi [1 ]
Yasui, Akira [2 ]
Miyata, Noriyuki [3 ]
Nohira, Hiroshi [1 ]
机构
[1] Tokyo City Univ, Setagaya Ku, Tokyo 1588557, Japan
[2] Japan Synchrotron Radiat Res Inst JASRI, Sayo, Hyogo 6795198, Japan
[3] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058568, Japan
关键词
hard X-ray photoelectron spectroscopy; metal-insulator-metal structure; interface dipole modulation; change in the chemical bonding state of Ti;
D O I
10.35848/1882-0786/ac9ae6
中图分类号
O59 [应用物理学];
学科分类号
摘要
Hard X-ray photoelectron spectroscopy was used to examine the interface dipole modulation of SiO2/1-monolayer titanium oxide/HfO2 stack embedded in a metal-insulator-metal structure. Reversible shifts in the Si 1 s, Hf 3d, and Ti 1 s photoelectron peaks were induced by electrical stress, and they indicate the switching of the potential profile inside the SiO2/titanium oxide/HfO2 stack. Moreover, a proportion change in the Ti3+ component correlates with the potential switching, and that correlation suggests that the structural change around the interface titanium atoms leads to the interface dipole modulation.
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页数:5
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