Evaluation of thermo-kinetic and absorption characteristics of pure desiccants and desiccant mixtures

被引:13
作者
Bhowmik, Mrinal [1 ]
Haldar, Sayan [3 ]
Dharmalingam, K. [3 ]
Muthukumar, P. [1 ,2 ]
Analakshmi, R. [3 ]
机构
[1] Indian Inst Technol Guwahati, Ctr Energy, Gauhati 781039, India
[2] Indian Inst Technol Guwahati, Dept Mech Engn, Gauhati 781039, India
[3] Indian Inst Technol Guwahati, Dept Chem Engn, Adv Energy & Mat Lab, Gauhati 781039, India
关键词
LiBr; CaCl2; Desiccant mixtures; XRD analysis; Absorption rate; TG-DSC analysis; LITHIUM;
D O I
10.1016/j.matpr.2020.02.430
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Air conditioning systems are used to control the air dry-bulb temperature and humidity level for human thermal comfort. In order to control the humidity level, air dry-bulb temperature needs to be brought down below its dew point temperature to condense out the moisture from the air. This eventually consumes a significant amount of total building energy in terms of electricity. Therefore, to minimize the energy consumption, researchers are stimulating their study towards an alternative latent heat load control system. In this regard, desiccant based sorption technologies are more effective compared to the conventional vapor compression system. Therefore, it is necessary to analyze the different desiccants' individual properties and their physical behavior in material perspective. In this study, an effort is devoted to explore the thermo-kinetic properties of pure LiBr, CaCl2, as well as their mixtures (LiBr: CaCl2 of 90:10; 85:15; 80:20 and 75:25) by X-ray diffraction (XRD), thermo-gravimetric (TG) and absorption rate, analyzes through numerous control experiments. The XRD study confirmed that peaks of CaCl2 and LiBr were shifted slightly for LiBr and CaCl2 mixtures due to interaction effects. The results of present investigation elucidated that mixtures of LiBr and CaCl2 showed less moisture regeneration cost than pure CaCl2 and all the mixtures revealed more rate of moisture absorption than pure LiBr and CaCl2. Further, 85:15 mixture of LiBr:CaCl2 showed higher rate of moisture absorption when compared to other prepared samples. (C) 2019 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the 10th International Conference of Materials Processing and Characterization.
引用
收藏
页码:1967 / 1971
页数:5
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