Chelated heteroatoms in polyoxometalates and the topological equivalence of {CoIII(en)} to type II cis-dioxometal centers.: Synthesis and structure of [{Co(en)(μ-OH)2Co(en)}{PW10O37Co(en)}2]8- and [K⊂{Co(en)WO4}{WO(H2O)}{PW9O34)2]12-

被引:61
作者
Belai, N [1 ]
Pope, MT [1 ]
机构
[1] Georgetown Univ, Washington, DC 20057 USA
关键词
D O I
10.1039/b509756h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first examples of polyoxometalate structures that incorporate embedded chelated heteroatoms point to new possibilities for stereochemical control of applications.
引用
收藏
页码:5760 / 5762
页数:3
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