Nanostructured-[CeO2, La2O3, C]/TiO2 Catalysts for Lignin Photodegradation

被引:24
作者
Rangel, R. [1 ]
Lopez Mercado, G. J. [1 ]
Bartolo-Perez, P. [2 ]
Garcia, R. [3 ]
机构
[1] Univ Michoacana, Div Estudios Posgrad, Fac Ingn Quim, Morelia 58060, Michoacan, Mexico
[2] CINVESTAV IPN, Dept Fis Aplicada, Unidad Merida, Merida 97310, Yuc, Mexico
[3] Univ Sonora, Dept Invest Fis, Hermosillo 83190, Sonora, Mexico
关键词
Nanotubes; Cerium Oxide; Lanthanum Oxide; Photocatalyst; UV Radiation; TIO2; PHOTOCATALYSIS; GAMMA-BI2MOO6; PHASE; WATER;
D O I
10.1166/sam.2012.1321
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The present paper is focused on the photodegradation study of lignin, dissolved in a water medium under three catalytic systems: CeO2 nanotubes/TiO2, La2O3 nanotubes/TiO2 and C nanotubes/TiO2. Photocatalytic reactions were conducted in a micro reactor batch system under UV irradiation. CeO2, La2O3 and TiO2 were synthesized by means of the sol-gel method followed by post hydrothermal synthesis of CeO2 and La2O3 to obtain the nanotubular structures, while C nanotubes were from Alfa Aesar. The catalysts were analyzed by means of XRD, SEM, BET, EDS, TEM. In order to optimize the yield reaction it was performed one experimental design. According to the results nanostructured CeO2, La2O3, C enhances the catalytic activity of TiO2, reaching in some cases degradation near to 60% in 25 minutes.
引用
收藏
页码:573 / 578
页数:6
相关论文
共 21 条
[1]  
Benjaram R., 2002, J PHYS CHEM B, V106, P5695
[2]   Titanium dioxide catalyzed photodegradation of lignin in industrial effluents [J].
Dahm, A ;
Lucia, LA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (25) :7996-8000
[3]   Phase analysis and oxygen storage capacity of ceria-lanthana-based TWC promoters prepared by sol-gel routes [J].
Deganello, F ;
Martorana, A .
JOURNAL OF SOLID STATE CHEMISTRY, 2002, 163 (02) :527-533
[4]   Role of the crystallite phase of TiO2 in heterogeneous photocatalysis for phenol oxidation in water [J].
Ding, Z ;
Lu, GQ ;
Greenfield, PF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (19) :4815-4820
[5]   Photodegradation of substituted stilbene compounds: What colors aging paper yellow? [J].
Durbeej, B ;
Eriksson, LA .
JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (25) :5677-5682
[6]   Buoyant Photocatalyst with Greatly Enhanced Visible-Light Activity Prepared through a Low Temperature Hydrothermal Method [J].
Han, Hui ;
Bai, Renbi .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (06) :2891-2898
[7]  
Hong O. X., 2006, REACT KINET CATAL LE, V88, P89
[8]   Photodegradation of gaseous volatile organic compounds (VOCs) using TiO2 photoirradiated by an ozone-producing UV lamp:: decomposition characteristics, identification of by-products and water-soluble organic intermediates [J].
Jeong, J ;
Sekiguchi, K ;
Lee, W ;
Sakamoto, K .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2005, 169 (03) :279-287
[9]   TiO2 photocatalysis of natural organic matter in surface water:: Impact on trihalomethane and haloacetic acid formation potential [J].
Liu, Sanly ;
Lim, May ;
Fabris, Rolando ;
Chow, Christopher ;
Drikas, Mary ;
Amal, Rose .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (16) :6218-6223
[10]   SURFACE-ACIDITY AND PHOTOCATALYTIC ACTIVITY OF TIO2, WO3 TIO2, AND MOO3 TIO2 PHOTOCATALYSTS [J].
PAPP, J ;
SOLED, S ;
DWIGHT, K ;
WOLD, A .
CHEMISTRY OF MATERIALS, 1994, 6 (04) :496-500