Microwave assisted enzymatic synthesis of speciality esters: A mini - review

被引：47

作者：

Khan, Nishat R. ^{[1
]}

Rathod, Virendra K. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Chem Engn, Mumbai 400019, Maharashtra, India

来源：

PROCESS BIOCHEMISTRY | 2018年 / 75卷

关键词：

Speciality esters; Lipases; Esterification; Sustainability; Microwave; LIPASE-CATALYZED SYNTHESIS; ORGANIC-SYNTHESIS; ENANTIOSELECTIVE ESTERIFICATION; ACID; IRRADIATION; RADIATION; SYNERGISM; TRANSESTERIFICATION; OPTIMIZATION; RESOLUTION;

D O I：

10.1016/j.procbio.2018.08.019

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Biocatalysis exhibits distinct improvement as compared to the chemical method of synthesis with respect to simplification of operating process, improvement in end product quality and minimization of by-product. However, long duration of synthesis, slow reaction rate and poor conversion limit the scope of biocatalysis in the industry. Currently there is also an increased demand for the use of green technology in chemical industry. Application of microwave irradiation to the biocatalytic synthesis can address the drawbacks of biocatalysis in the industry. Microwave energy creates rampant localized super heating which enhances the reaction rate and reduces the synthesis time significantly. The present mini review article gives a brief account on uses of microwave energy in enzyme processed synthesis of various speciality esters that find application in chemical industries. It briefly discusses various aspects like mechanism, instrumentation, process variables, enzyme stability, kinetics and scalability approach.

引用

页码：89 / 98

页数：10

共 50 条

[21] Approaches to convert Mucor circinelloides lipid into biodiesel by enzymatic synthesis assisted by microwave irradiations [J].

Carvalho, Ana Karine F. ;

Bento, Heitor B. S. ;

Izario Filho, Held J. ;

de Castro, Heizir F. .

RENEWABLE ENERGY, 2018, 125 :747-754

[22] Microwave-assisted synthesis of benzothiazoleurea derivatives [J].

Chen, Wenbin ;

Li, Kejian ;

Wang, Yong ;

Xi, Zhen .

JOURNAL OF CHEMICAL RESEARCH, 2010, (02) :75-79

[23] Microwave-Assisted Synthesis of Cinnamyl Long Chain Aroma Esters [J].

Worzakowska, Marta .

MOLECULES, 2015, 20 (06) :10594-10603

[24] Synthesis of esters of substituted phenolic acids by microwave assisted wittig reaction [J].

Spasova, M ;

Bankova, V ;

Ivanova, G ;

Pajpanova, T ;

Milkova, T .

OXIDATION COMMUNICATIONS, 2006, 29 (01) :172-175

[25] Microwave-assisted NaHSO4-catalyzed synthesis of ricinoleic glycol ether esters [J].

Zhang, Haifei ;

Zhu, Fengfan ;

Xu, Yuan ;

Zhang, Xiaoxiang ;

Zhu, Xinbao .

SYNTHETIC COMMUNICATIONS, 2017, 47 (05) :486-495

[26] Biocatalytic synthesis of monoterpene esters - A review study on the phylogenetic evolution of biocatalysts [J].

Staudt, Amanda ;

Brack, Yannik ;

Itabaiana Jr, Ivaldo ;

Leal, Ivana Correa Ramos .

MOLECULAR CATALYSIS, 2022, 528

[27] Microwave Assisted Enzymatic Synthesis of Fatty Acid Sugar Ester in Ionic Liquid-tert-Butanol Biphasic Solvent System [J].

Rahman, Mohd. Basyaruddin Abdul ;

Arumugam, Mahashanon ;

Khairuddin, Nik Sasha Khatrina ;

Abdulmalek, Emilia ;

Basri, Mahiran ;

Salleh, Abu Bakar .

ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (11) :5058-5062

[28] ENZYMATIC SYNTHESIS OF CYCLOOLIGOSACHARIDE ESTERS [J].

Lukasiewicz, Marcin .

20TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY (ECSOC), 2016,

[29] Continuous-Flow Chemo and Enzymatic Synthesis of Monoterpenic Esters with Integrated Purification [J].

Adarme, Carlos A. A. ;

Leao, Raquel A. C. ;

de Souza, Stefania P. ;

Itabaiana, Ivaldo, Jr. ;

de Souza, Rodrigo O. M. A. ;

Rezende, Claudia M. .

MOLECULAR CATALYSIS, 2018, 453 :39-46

[30] Efficient microwave-assisted synthesis of glycerol monodecanoate [J].

Mhanna, Ali ;

Chupin, Lucie ;

Brachais, Claire-Helene ;

Chaumont, Denis ;

Boni, Gilles ;

Brachais, Laurent ;

Couvercelle, Jean-Pierre ;

Lecamp, Laurence ;

Plasseraud, Laurent .

EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2018, 120 (01)

← 1 2 3 4 5 →