Determination of bisphenol A in canned foods by immunoaffinity chromatography, HPLC, and fluorescence detection

被引:118
作者
Braunrath, R [1 ]
Podlipna, D [1 ]
Padlesak, S [1 ]
Cichna-Markl, M [1 ]
机构
[1] Univ Vienna, Dept Analyt & Food Chem, A-1090 Vienna, Austria
关键词
bisphenol A; migration; canned food; food analysis; immunoaffinity chromatography; sol-gel;
D O I
10.1021/jf051525j
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Bisphenol A (BPA) concentrations were determined in canned beverages, fruits, vegetables, and fat-containing foodstuffs bought in Austrian supermarkets. The analysis method consisted of sol-gel immunoaffinity chromatography followed by high-performance liquid chromatography with fluorescence detection. With one exception traces of BPA were detected in all samples. BPA recovery strongly depended on the food matrix, ranging from 27% in goulash to 103% in a lemon soft drink. The results obtained allow a more realistic picture of the BPA exposure caused by cans with an epoxy resin protective coating because-in contrast to several previous studies-only those fractions of the can contents that are actually consumed were analyzed. BIPA concentrations ranging from 0.1 ng/mL (lemon soft drink) to 38 ng/g (ready-to eat soup from Thailand) were significantly lower than the European Union migration limit of 0.6 mg of BPA/kg of food.
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页码:8911 / 8917
页数:7
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