Visible-light attachment of Si-C linked functionalized organic monolayers on silicon surfaces

被引：44
作者：
de Smet, LCPM
Pukin, AV
Sun, QY
Eves, BJ
Lopinski, GP
Visser, GM
Zuilhof, H
Sudhölter, EJR
机构：
[1] Univ Wageningen & Res Ctr, Organ Chem Lab, NL-6703 HB Wageningen, Netherlands
[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
来源：
APPLIED SURFACE SCIENCE | 2005年 / 252卷 / 01期
关键词：
visible light; hydrosilylation; organic monolayers; receptors; biosensors; HYDROGEN-TERMINATED SILICON; SELF-ASSEMBLED MONOLAYERS; EXTREMELY MILD ATTACHMENT; ALKYL MONOLAYERS; DNA; HYBRIDIZATION; SI(111); MICROSCOPY; SI(100);
D O I：
10.1016/j.apsusc.2005.01.107
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Organic monolayers on hydrogen-terminated silicon surfaces were prepared under extremely mild conditions using visible light and analyzed by a variety of surface-sensitive techniques: (angle-resolved) X-ray photoelectron spectroscopy (ARXPS), scanning tunneling microscopy (STM), high-resolution electron energy loss spectroscopy (HREELS), and attenuated total reflection infrared spectroscopy (ATR-IR). Detailed XPS and STM analysis of non-functionalized monolayers, displays detailed mechanistic and structural,information. Additionally, we present the first attachment of a disaccharide to the silicon surface, and a characterization thereof by ATR-IR and HREELS. (c) 2005 Elsevier B.V. All rights reserved.
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页码：24 / 30
页数：7
相关论文
共 30 条
[11]   Structure and reactivity of mixed co-carboxyalkyl/alkyl monolayers on silicon: ATR-FTIR spectroscopy and contact angle titration [J].
Liu, YJ ;
Navasero, NM ;
Yu, HZ .
LANGMUIR, 2004, 20 (10) :4039-4050
[12]   Hydrophobic/hydrophilic interactions of cytochrome c with functionalized self-assembled monolayers on silicon [J].
Moré, SD ;
Hudecek, J ;
Urisu, T .
SURFACE SCIENCE, 2003, 532 :993-998
[13]  
Pike AR, 2002, ANGEW CHEM INT EDIT, V41, P615, DOI 10.1002/1521-3773(20020215)41:4<615::AID-ANIE615>3.3.CO
[14]  
2-P
[15]   Highly stable Si-C linked functionalized monolayers on the silicon (100) surface [J].
Sieval, AB ;
Demirel, AL ;
Nissink, JWM ;
Linford, MR ;
van der Maas, JH ;
de Jeu, WH ;
Zuilhof, H ;
Sudholter, EJR .
LANGMUIR, 1998, 14 (07) :1759-1768
[16]  
Sieval AB, 2000, ADV MATER, V12, P1457, DOI 10.1002/1521-4095(200010)12:19<1457::AID-ADMA1457>3.0.CO
[17]  
2-#
[18]   An improved method for the preparation of organic monolayers of 1-alkenes on hydrogen-terminated silicon surfaces [J].
Sieval, AB ;
Vleeming, V ;
Zuilhof, H ;
Sudhölter, EJR .
LANGMUIR, 1999, 15 (23) :8288-8291
[19]   Amino-terminated organic monolayers on hydrogen-terminated silicon surfaces [J].
Sieval, AB ;
Linke, R ;
Heij, G ;
Meijer, G ;
Zuilhof, H ;
Sudhölter, EJR .
LANGMUIR, 2001, 17 (24) :7554-7559
[20]   Monolayers of 1-alkynes on the H-terminated Si(100) surface [J].
Sieval, AB ;
Opitz, R ;
Maas, HPA ;
Schoeman, MG ;
Meijer, G ;
Vergeldt, FJ ;
Zuilhof, H ;
Sudhölter, EJR .
LANGMUIR, 2000, 16 (26) :10359-10368
123