Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis

被引：42
|
作者：
Boersma, Arnold J. [1 ]
de Bruin, Bas [2 ]
Feringa, Ben L. [1 ]
Roelfes, Gerard [1 ]
机构：
[1] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands
[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 18期
关键词：
ARTIFICIAL TRANSFER HYDROGENASES; TERNARY COPPER(II) COMPLEXES; DIELS-ALDER REACTION; DESIGN;
D O I：
10.1039/c2cc17350f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
DNA-based catalysis can be used to control the enantioselectivity of copper-catalysed Diels-Alder and Friedel-Crafts reactions to produce either enantiomer of the product by changing the denticity of the ligand coordinated to the Cu(II) ion, even though the DNA adopts a right handed helical conformation only.
引用
收藏
页码：2394 / 2396
页数：3
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