Lewis Acid-Promoted Addition of 1,3-Bis(silyl)propenes to Aldehydes: A Route to 1,3-Dienes

被引：21

作者：

Borg, Tessie ^{[1
]}

Tuzina, Pavel ^{[1
]}

Somfai, Peter ^{[1
,2
]}

机构：

[1] Organ Chem Royal Inst Technol, KTH Chem Sci & Engn, S-10044 Stockholm, Sweden

[2] Univ Tartu, Inst Technol, EE-50441 Tartu, Estonia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 19期

基金：

瑞典研究理事会;

关键词：

DIELS-ALDER REACTION; OLEFINATION REACTION; WITTIG OLEFINATION; STEREOCHEMISTRY; ALLYLSILANES; MECHANISM; DIENES; NICKEL;

D O I：

10.1021/jo2013466

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Lewis acid-promoted addition of 1,3-bis(silyl)-propenes to aldehydes to provide the corresponding (E)-1,3-dienes in excellent stereoselectivity and good to excellent yields is reported. The procedure is mild, base-free, and operationally straightforward.

引用

页码：8070 / 8075

页数：6

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