Theoretical Study of Zero Field Splitting Parameters of Fe3+ doped TlInS2 Single Crystal

被引：0

作者：

Kripal, R. ^{[1
]}

Shukla, L. C. ^{[1
]}

Tripathi, U. M. ^{[1
]}

机构：

[1] Univ Allahabad, Dept Phys, EPR Lab, Allahabad 211002, Uttar Pradesh, India

来源：

ACTA PHYSICA POLONICA A | 2022年 / 141卷 / 05期

关键词：

inorganic compounds; single crystal; crystal fields; electron paramagnetic resonance; SPIN-HAMILTONIAN PARAMETERS; ELECTRON-PARAMAGNETIC-RESONANCE; SUPERPOSITION MODEL; ENERGY-LEVELS; GROUND-STATE; IONS; EPR; EMR;

D O I：

10.12693/APhysPolA.141.530

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Crystal field parameters and zero field splitting parameters of Fe3+ doped TlInS2 crystals are studied theoretically at room temperature using the superposition model and the perturbation theory. The zero field splitting parameters are determined without and with local distortion. These parameters give reasonable agreement with the experimental values when local distortion is taken into consideration. The theoretical study supports the experimental result that Fe3+ substitutes for In3+ in the TlInS2 crystal.

引用

页码：530 / 534

页数：5

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