Preparation of LiFePO4/C in a reductive atmosphere generated by windward aerobic decomposition of glucose

被引：16

作者：

Wang, Shengping ^{[1
]}

Zhou, Chenggang ^{[1
]}

Zhou, Quan ^{[1
]}

Ni, Gang ^{[1
]}

Wu, Jinping ^{[1
]}

机构：

[1] China Univ Geosci Wuhan, Sustainable Energy Lab, Wuhan 430074, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2011年 / 196卷 / 11期

关键词：

Lithium iron phosphate; Carbon coating; Glucose; Windward aerobic decomposition; LITHIUM-ION BATTERIES; CARBON-COATED LIFEPO4; ELECTROCHEMICAL PROPERTIES; CATHODE MATERIALS; IRON PHOSPHATE; TEMPERATURE; COMPOSITES; PERFORMANCE; PYROLYSIS;

D O I：

10.1016/j.jpowsour.2011.01.100

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the preparation of LiFePO4/C electrode materials by thermal treating the hydrothermal LiFePO4/C precursors in a reductive atmosphere from windward aerobic decomposition of glucose. XRD and ESEM characterization indicate that the procedure produces well carbon coated single-phase orthorhombic LiFePO4 with small and evenly distributed particle-sizes. Comparing with the typical Ar/H-2 reductive atmosphere, samples from this procedure host larger initial discharge capacity (147.9 vs. 129.8 mAh g(-1)) and excellent reversibility with a capacity reservation of 96.9% after 50 cycles at 0.1 C. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：5143 / 5146

页数：4

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