Deposition of chromium hexacarbonyl on alumina in a fluidized bed reactor

被引：7
|
作者：
Myllyoja, S [1 ]
Pakkanen, TA [1 ]
机构：
[1] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 136卷 / 02期
关键词：
chromium hexacarbonyl; Cr(CO)(6); alumina; Al2O3; fluidized bed reactor; DRIFT;
D O I：
10.1016/S1381-1169(98)00055-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cr(CO)(6)/Al2O3 samples were prepared in a fluidized bed reactor by vapour phase adsorption of chromium hexacarbonyl under nitrogen flow. The preparation of the samples were followed by diffuse reflectance IR spectroscopy and the chromium content was determined by EDXRF. Deposition and pulse techniques were used to vaporize the hexacarbonyl on the alumina surface. The pulse technique proved to be very effective when higher chromium contents were desired. The temperature of the calcination (500 degrees C/300 degrees C) also had a significant effect on the amount of chromium adsorbed. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：153 / 160
页数：8
相关论文
共 50 条
  • [1] Controlled deposition of chromium hexacarbonyl on silica surfaces in a fluidised bed reactor
    Myllyoja, S
    Pakkanen, TA
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 156 (1-2) : 195 - 203
  • [2] Silicon oxide thin film deposition on alumina in a circulating fluidized bed reactor
    Park, SM
    Jung, SH
    Park, SH
    Kim, SD
    ON THE CONVERGENCE OF BIO-INFORMATION-, ENVIRONMENTAL-, ENERGY-, SPACE- AND NANO-TECHNOLOGIES, PTS 1 AND 2, 2005, 277-279 : 577 - 582
  • [3] A fluidized bed reactor for low temperature deposition
    Suvanto, S
    Pakkanen, TA
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 125 (2-3) : 91 - 96
  • [4] Alumina atomic layer deposition nanocoatings on primary diamond particles using a fluidized bed reactor
    Liang, Xinhua
    Zhan, Guo-Dong
    King, David M.
    McCormick, Jarod A.
    Zhang, John
    George, Steven M.
    Weimer, Alan W.
    DIAMOND AND RELATED MATERIALS, 2008, 17 (02) : 185 - 189
  • [5] Nickel and copper deposition on fine alumina particles by using the chemical vapor deposition-circulation fluidized bed reactor technique
    Yee-Wen Yen
    Sinn-Wen Chen
    Journal of Materials Science, 2000, 35 : 1439 - 1444
  • [6] Nickel and copper deposition on fine alumina particles by using the chemical vapor deposition-circulation fluidized bed reactor technique
    Yen, YW
    Chen, SW
    JOURNAL OF MATERIALS SCIENCE, 2000, 35 (06) : 1439 - 1444
  • [7] Plasma deposition of allylamine on polymer powders in a fluidized bed reactor
    Tatoulian, M
    Brétagnol, FR
    Arefi-Khonsari, F
    Amouroux, J
    Bouloussa, O
    Rondelez, F
    Paul, AJ
    Mitchell, R
    PLASMA PROCESSES AND POLYMERS, 2005, 2 (01) : 38 - 44
  • [8] Mass transfer model of chromium reduction in a fluidized bed electrochemical reactor
    Hu, X
    Bautista, RG
    SEPARATION SCIENCE AND TECHNOLOGY, 1997, 32 (10) : 1769 - 1785
  • [9] FLUIDIZED BED REACTOR
    SHIRAI, T
    KOGYO KAGAKU ZASSHI, 1961, 64 (10): : 1725 - &
  • [10] Fluidized Bed Chemical Vapor Deposition of Copper on Micronic Alumina Powders
    Jellal, Ilyass
    Vergnes, Hugues
    Caussat, Brigitte
    CHEMICAL ENGINEERING & TECHNOLOGY, 2024, 47 (12)
12345