Controllable fabrication of cadmium phthalocyanine nanostructures immobilized on electrospun polyacrylonitrile nanofibers with high photocatalytic properties under visible light

被引:41
作者
Guo, Zengcai
Shao, Changlu [1 ]
Mu, Jingbo
Zhang, Mingyi
Zhang, Zhenyi
Zhang, Peng
Chen, Bin
Liu, Yichun
机构
[1] Ctr Adv Optoelect Funct Mat Res, Changchun 130024, Peoples R China
基金
中国国家自然科学基金;
关键词
Phthalocyanine; Immobilization; Composite nanofibers; Reuse; Photocatalysis; ORGANIC PHOTOVOLTAIC CELLS; COPPER PHTHALOCYANINE; TIO2; NANOPARTICLES; THIN-FILMS; DEGRADATION; IRRADIATION; OXIDATION; COPOLYMER;
D O I
10.1016/j.catcom.2011.02.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel photocatalyst of nanostructured cadmium phthalocyanine (CdPc) immobilized on the surface of polyacrylonitrile (PAN) nanofibers had been successfully fabricated by a simple combination of electrospinning technique and the solvent-thermal process. FE-SEM micrographs indicated that the nanostructured CdPc uniformly immobilized on the surface of PAN nanofibers without agglomeration. And the obtained CdPc/PAN composite nanofibers exhibited high visible light photocatalytic activity for the degradation of rhodamine B. Moreover, this photocatalyst could be easily separated for reuse due to the one-dimensional nanostructural property of the CdPc/PAN composite nanofibers. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:880 / 885
页数:6
相关论文
共 30 条
[1]   Studies on polymorphic modifications of copper phthalocyanine [J].
Achar, BN ;
Lokesh, KS .
JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (06) :1987-1993
[2]   Influence of polyaniline and phthalocyanine hole-transport layers on the electrical performance of light-emitting diodes using MEH-PPV as emissive material [J].
Brirto Santos, Joao Claudio ;
Paterno, Leonardo Giordano ;
Tadeu Dirani, Ely Antonio ;
Fonseca, Fernando Josepetti ;
de Andrade, Adnei M. .
THIN SOLID FILMS, 2008, 516 (10) :3184-3188
[3]   The effect of background irradiation on photocatalytic efficiencies of TiO2 thin films [J].
Cen, HW ;
Li, XJ ;
He, MX ;
Zheng, SJ ;
Feng, MZ .
CHEMOSPHERE, 2006, 62 (05) :810-816
[4]   Preparation of a thermosensitive cobalt phthalocyanine/N-isopropylacrylamide copolymer and its catalytic activity on thiol [J].
Chen, Wenxing ;
Zhao, Baoyan ;
Pan, Yong ;
Yao, Yuyuan ;
Lu, Shenshui ;
Chen, Shiliang ;
Du, Lijuan .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 300 (02) :626-632
[5]   Photocatalytic oxidation of 4-chlorophenol using thermosensitive zinc phthalocyanine copolymer under visible light irradiation [J].
Chen WenXing ;
Lue WangYang ;
Shen XiaoYuan ;
Yao YuYuan .
SCIENCE CHINA-CHEMISTRY, 2010, 53 (03) :638-644
[6]   Sequential addition of H2O2, pH and solvent effects as key factors in the oxidation of 2,4,6-trichlorophenol catalyzed by iron tetrasulfophthalocyanine [J].
Hadasch, A ;
Sorokin, A ;
Rabion, A ;
Meunier, B .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (01) :45-51
[7]   Preparation of highly oriented copper phthalocyanine film by molecular templating effects for organic field-effect transistor [J].
Hong, Fei ;
Guo, Xinan ;
Zhang, Hao ;
Wei, Bin ;
Zhang, Jianhua ;
Wang, Jun .
ORGANIC ELECTRONICS, 2009, 10 (06) :1097-1101
[8]   Aluminum phthalocyanine chloride/C60 organic photovoltaic cells with high open-circuit voltages [J].
Kim, Do Young ;
So, Franky ;
Gao, Yongli .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (09) :1688-1691
[9]   Nanostructures for enzyme stabilization [J].
Kim, J ;
Grate, JW ;
Wang, P .
CHEMICAL ENGINEERING SCIENCE, 2006, 61 (03) :1017-1026
[10]   Determination of chemical oxygen demand values by a photocatalytic oxidation method using nano-TiO2 film on quartz [J].
Li, JQ ;
Li, LP ;
Zheng, L ;
Xian, YZ ;
Jin, LT .
TALANTA, 2006, 68 (03) :765-770