Original Transition Metal→Indium Interactions upon Coordination of a Triphosphine-Indane

被引：66

作者：

Derrah, Eric J. ^{[1
,2
]}

Sircoglou, Marie ^{[1
,2
]}

Mercy, Maxime ^{[5
,6
]}

Ladeira, Sonia ^{[3
]}

Bouhadir, Ghenwa ^{[1
,2
]}

Miqueu, Karinne ^{[4
]}

Maron, Laurent ^{[5
,6
]}

Bourissou, Didier ^{[1
,2
]}

机构：

[1] Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France

[2] CNRS, LHFA, UMR 5069, F-31062 Toulouse, France

[3] Struct Federat Toulousaine Chim Mol FR 2599, F-31062 Toulouse 9, France

[4] Univ Pau & Pays Adour, Inst Pluridisciplinaire Rech Environm & Mat, CNRS, UMR 5254, F-64053 Pau 09, France

[5] Univ Toulouse, INSA, UPS, LPCNO, F-31077 Toulouse, France

[6] CNRS, LPCNO, UMR 5215, F-31077 Toulouse, France

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 04期

关键词：

AMBIPHILIC LIGAND; METAL-COMPLEXES; INCP-ASTERISK; INDIUM; RHODIUM; BORANE; CHEMISTRY; COMPOUND; PLATINUM; GA;

D O I：

10.1021/om1011769

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The triphosphine-indane TPI([o-i-Pr2P(C6H4)](3)In) has been prepared and found to react with [Pd(P-t-Bu-3)(2)] and [AuCl(SMe2)]. According to X-ray diffraction analyses and DFT calculations, the ensuing complexes both display original donor acceptor M In interactions, although of markedly different nature and magnitude.

引用

页码：657 / 660

页数：4

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