Electrochemistry and umpolung reactions: New tools for solving synthetic challenges of structure and location

被引：38

作者：

Tang, Feili ^{[1
]}

Chen, Ceng ^{[1
]}

Moeller, Kevin D. ^{[1
]}

机构：

[1] Washington Univ, Dept Chem, St Louis, MO 63130 USA

来源：

SYNTHESIS-STUTTGART | 2007年 / 21期

关键词：

electron transfer; umpolung; cyclizations; site-selective reactions; Heck reactions;

D O I：

10.1055/s-2007-990835

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrochemistry is a powerful tool for initiating new umpolung reactions. In this paper, two examples are provided. One demonstrates the use of electrochemistry for reversing the polarity of known functional groups and triggering carbon-carbon bond formation. The second demonstrates the use of electrochemistry for reversing the polarity of a chemical reagent, a technique that allows for spatially locating synthetic transformations on addressable chips.

引用

页码：3411 / 3420

页数：10