Advances in Transfer Hydrogenation of Carbonyl Compounds in Water

被引：45
作者：
He, Yan-Mei [1 ,2 ]
Fan, Qing-Hua [1 ,2 ]
机构：
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
来源：
CHEMCATCHEM | 2015年 / 7卷 / 03期
基金：
中国国家自然科学基金;
关键词：
carbonyl compounds; cyclometalated complexes; iridium; hydrogenation; water; ASYMMETRIC TRANSFER HYDROGENATION; CHEMOSELECTIVE TRANSFER HYDROGENATION; REDUCTIVE AMINATION; AROMATIC KETONES; COMPLEXES; ALDEHYDES; CATALYSTS; IRIDIUM; RUTHENIUM; EFFICIENT;
D O I：
10.1002/cctc.201402883
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Clean and fast: Transfer hydrogenation of carbonyl compounds in water is attracting increasing attention. This Highlight describes the recent advances in this field made using half-sandwich metal complexes and iridacycle-type complexes as a new kind of versatile catalyst that exhibits high efficiency and chemoselectivity, as well as a broad substrate scope in water as the reaction medium. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：398 / 400
页数：3
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