Copper-Catalyzed Cross-Coupling of Alkyl and Phosphorus Radicals for C(sp3)-P Bond Formation

被引：33

作者：

Li, Cheng-Kun ^{[1
]}

Tao, Ze-Kun ^{[1
]}

Shoberu, Adedamola ^{[1
]}

Zhang, Wei ^{[2
]}

Zou, Jian-Ping ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Jiangsu, Peoples R China

[2] Univ Massachusetts Boston, Dept Chem, Boston, MA 02125 USA

来源：

ORGANIC LETTERS | 2022年

基金：

中国国家自然科学基金;

关键词：

AMP Exception; ALKENES; ACIDS; ARYL; OXYPHOSPHORYLATION; PHOSPHINATION; PHOSPHONATES; DIOXYGEN;

D O I：

10.1021/acs.orglett.2c02454

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Cu-I-catalyzed cross-coupling of alkyl-and phosphorus-centered radicals for C(sp(3))-P bond formation is introduced. Diacyl peroxides, generated in situ from aliphatic acids and H2O2, serve as a source for alkyl radicals and also an initiator for the generation of phosphorus radicals from H-P(O) compounds.

引用

页码：6083 / 6087

页数：5

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