The rich physics of A-site-ordered quadruple perovskite manganites AMn7O12

被引：17
作者：
Belik, Alexei A. [1 ]
Johnson, Roger D. [2 ]
Khalyavin, Dmitry D. [3 ]
机构：
[1] Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, Namiki 1-1, Tsukuba, Ibaraki 3050044, Japan
[2] UCL, Dept Phys & Astron, Gower St, London WC1E 6BT, England
[3] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England
来源：
DALTON TRANSACTIONS | 2021年 / 50卷 / 43期
关键词：
HIGH-PRESSURE SYNTHESIS; CRYSTAL-STRUCTURE; X-RAY; NEUTRON-DIFFRACTION; CHARGE; PHASE; TRANSITION; DISTORTION; SRMN7O12; CAMN7O12;
D O I：
10.1039/d1dt02992d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Perovskite-structure AMnO(3) manganites played an important role in the development of numerous physical concepts such as double exchange, small polarons, electron-phonon coupling, and Jahn-Teller effects, and they host a variety of important properties such as colossal magnetoresistance and spin-induced ferroelectric polarization (multiferroicity). A-site-ordered quadruple perovskite manganites AMn(7)O(12) were discovered shortly after, but at that time their exploration was quite limited. Significant progress in their understanding has been reached in recent years after the wider use of high-pressure synthesis techniques needed to prepare such materials. Here we review this progress, and show that the AMn(7)O(12) compounds host rich physics beyond the canonical AMnO(3) materials.
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收藏
页码：15458 / 15472
页数：15
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