PCDD/F reduction in incinerator flue gas by adding urea to RDF feedstock

被引:34
作者
Ruokojärvi, P
Tuppurainen, K
Mueller, C
Kilpinen, P
Ruuskanen, J
机构
[1] Univ Kuopio, Dept Environm Sci, FIN-70211 Kuopio, Finland
[2] Univ Kuopio, Dept Chem, FIN-70211 Kuopio, Finland
[3] Abo Akad Univ, Proc Chem Grp, FIN-20520 Turku, Finland
基金
芬兰科学院;
关键词
PCDD; PCDF; chlorophenols; RDF; inhibition; urea; pilot incinerator;
D O I
10.1016/S0045-6535(00)00135-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The effect of urea on PCDD/F formation in a pilot incinerator was studied by incinerating urea with refuse-derived fuel (RDF) at three concentrations (0.1%, 0.5% and 1.0% of the fuel feed). A distinct reduction in both PCDD/F and chlorophenol concentrations could be noticed when urea was introduced into the system. partial-least-square (PLS) analysis of the data showed the importance of certain chlorophenol isomers as PCDD/F precursors, pointing to the possibility that the impact point of the urea inhibitor could be before the precursor molecules, i.e. chlorophenols, have been formed. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:199 / 205
页数:7
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