Density, speed of sound and refractive index of mixtures containing 2-phenoxyethanol with propanol or butanol at various temperatures

被引:29
|
作者
Makhlouf, Hamdi [1 ]
Munoz-Rujas, Natalia [2 ]
Aguilar, Fernando [2 ]
Belhachemi, Boucif [1 ]
Montero, Eduardo A. [2 ]
Bahadur, Indra [3 ]
Negadi, Latifa [1 ,4 ,5 ]
机构
[1] Univ Tlemcen, Fac Sci, Dept Chem, POB 119, Tilimsen 13000, Algeria
[2] Univ Burgos, Dept Ingn Electromecan, Escuela Politecn Super, Ave Cantabria S-N, Burgos 09006, Spain
[3] North West Univ, Fac Nat & Agr Sci, Mat Sci Innovat & Modelling MaSIM Res Focus Area, Dept Chem,Sch Math & Phys Sci, Mafikeng Campus,Private Bag X2046, ZA-2735 Mmabatho, South Africa
[4] Univ Tlemcen, Lab Themodynam Appl & Modelisat Mol, LATA2M, POB 119, Tilimsen 13000, Algeria
[5] Univ KwaZulu Natal, Sch Engn, Thermodynam Res Unit, Howard Coll Campus,King George V Ave, ZA-4041 Durban, South Africa
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2019年 / 128卷
关键词
2-Phenoxyethanol; Alcohol; Density; Speed of sound; Refractive index; Redlich-Kister polynomial equation; EXCESS MOLAR VOLUMES; VAPOR-LIQUID-EQUILIBRIUM; PLUS ALIPHATIC-ALCOHOLS; BINARY-MIXTURES; 298.15; K; TERNARY MIXTURES; SURFACE-TENSION; THERMODYNAMIC PROPERTIES; MOLECULAR-INTERACTIONS; ISOMERIC BUTANOLS;
D O I
10.1016/j.jct.2018.08.029
中图分类号
O414.1 [热力学];
学科分类号
摘要
In this work, we reported the new experimental data of densities, speeds of sound, and refractive indices for four binary mixtures: {2-phenoxyethanol (2PhEE) + 1-propanol or 2-propanol or 1-butanol or 2-butanol) over the entire composition range and at temperatures of (293.15, 303.15, 313.15 and 323.15) K and at pressure p = 0.1 MPa. From these experimental data, thermodynamics properties: excess molar volume, isentropic compressibility, deviation in isentropic compressibility and deviation in refractive indices were calculated. Excess molar volume, deviation in isentropic compressibility and deviation in refractive indices data have been correlated using the Redlich-Kister equation. From the obtained results, a discussion was carried out in terms of nature of intermolecular interactions and structure factors in these binary mixtures. (C) 2018 Elsevier Ltd.
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页码:394 / 405
页数:12
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