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Visible light photocatalysis by metal-to-metal charge transfer for degradation of methyl orange
被引:10
|作者:
Ireland, C. P.
[1
]
Palgrave, R. G.
[1
,3
]
Bennett, S. C.
[2
]
Smith, A. W. J.
[2
]
Clark, J. H.
[1
]
Darwent, J. R.
[1
]
Claridge, J. B.
[1
]
Poulston, S.
[2
]
Rosseinsky, M. J.
[1
]
机构:
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
[2] Johnson Matthey Technol Ctr, Reading RG4 9NH, Berks, England
[3] UCL, Dept Chem, Christopher Ingold Labs, 20 Gordon St, London WC1H 0AJ, England
基金:
英国工程与自然科学研究理事会;
关键词:
SEMICONDUCTOR PHOTOCATALYSIS;
WATER;
TIO2;
CATALYSTS;
EFFICIENT;
NB2O5;
CR;
D O I:
10.1039/c6ta00192k
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
We have impregnated chromium(III) onto a high surface area particulate niobium oxide to make bulk oxide-oxide interfaces, identifying by a combination of X-ray photoelectron spectroscopy and diffuse reflectance the exact energy of the metal-to-metal charge transfer transition that is responsible for the visible light photocatalytic decomposition of methyl orange.
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页码:12479 / 12486
页数:8
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