Synthesis and photophysical properties of α,ω-bis(terpyridine)oligothiophenes

被引：26
|
作者：
Svoboda, Jan [1 ]
Stenclova, Pavla [1 ]
Uhlik, Filip [1 ]
Zednik, Jiri [1 ]
Vohlidal, Jiri [1 ]
机构：
[1] Charles Univ Prague, Dept Phys & Macromol Chem, Fac Sci, CZ-12840 Prague 2, Czech Republic
来源：
TETRAHEDRON | 2011年 / 67卷 / 01期
关键词：
RUTHENIUM(II) COMPLEXES; SUPRAMOLECULAR POLYMERS; TERPYRIDINE LIGANDS; METAL; THIOPHENE;
D O I：
10.1016/j.tet.2010.11.039
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Four novel fully pi-conjugated alpha,omega-bis(terpyridine)oligothiophenes characterized by NMR, IR, and HR-mass spectroscopy are presented and their electronic absorption/emission and redox properties are described based on both experiments and theoretical calculations. These compounds can be potentially utilized as building blocks for preparation of conjugated metallo-supramolecular polymers or dynamers and related functional materials. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：75 / 79
页数：5
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