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Synthesis and photophysical properties of α,ω-bis(terpyridine)oligothiophenes
被引:26
|作者:
Svoboda, Jan
[1
]
Stenclova, Pavla
[1
]
Uhlik, Filip
[1
]
Zednik, Jiri
[1
]
Vohlidal, Jiri
[1
]
机构:
[1] Charles Univ Prague, Dept Phys & Macromol Chem, Fac Sci, CZ-12840 Prague 2, Czech Republic
来源:
关键词:
RUTHENIUM(II) COMPLEXES;
SUPRAMOLECULAR POLYMERS;
TERPYRIDINE LIGANDS;
METAL;
THIOPHENE;
D O I:
10.1016/j.tet.2010.11.039
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Four novel fully pi-conjugated alpha,omega-bis(terpyridine)oligothiophenes characterized by NMR, IR, and HR-mass spectroscopy are presented and their electronic absorption/emission and redox properties are described based on both experiments and theoretical calculations. These compounds can be potentially utilized as building blocks for preparation of conjugated metallo-supramolecular polymers or dynamers and related functional materials. (C) 2010 Elsevier Ltd. All rights reserved.
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页码:75 / 79
页数:5
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