A highly unsaturated platinum-rhenium cluster complex that adds an unusually large amount of hydrogen

被引：33
作者：
Adams, RD [1 ]
Captain, B [1 ]
机构：
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 17期
关键词：
cluster compounds; electron counting; hydrogen; platinum; rhenium;
D O I：
10.1002/anie.200500086
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Where have all the electrons gone? The complex [Pt3Re2(CO)6(PtBu3) 3] (1) containing a trigonal bipyramidal metal cluster is unsaturated by the amount of 10 valence electrons. Compound 1 reacts with hydrogen by adding three equivalents to form the hexahydrido complex 2. The metal cluster in 2 is similar to that of 1, but contains one bridging hydrido ligand on each of the Re-Pt bonds. Pt blue, Re green. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：2531 / 2533
页数：3
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