Metal-organic framework ZIF-8 for exceptional HCl removal from Hydrogen gas by reaction

被引：10
|
作者：
Sharma, Ravi [1 ]
Cousin-Saint-Remi, Julien [1 ]
Tiriana, Segato [2 ]
Delplancke, Marie-Paule [2 ]
Pletincx, Sven [3 ]
Baert, Kitty [3 ]
Hauffman, Tom [3 ]
Terryn, Herman [3 ]
Baron, Gino, V [1 ]
Denayer, Joeri F. M. [1 ]
机构：
[1] Vrije Univ Brussel, Chem Engn Dept, B-1050 Ixelles, Belgium
[2] Univ Libre Bruxelles, Dept Mat Engn Characterizat Synth & Recycling, B-105 Brussels, Belgium
[3] Vrije Univ Brussel, Electrochem & Surface Engn Res Grp, B-105 Ixelles, Belgium
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2022年 / 47卷 / 47期
关键词：
Breakthrough experiment; Metal-organic framework; Hydrogen gas; Hydrogen chloride; ZIF-8; ADSORPTION; SEPARATION; CHLORIDE;
D O I：
10.1016/j.ijhydene.2022.04.244
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the production of hydrogen gas, the removal of hydrogen chloride (HCl) is of particular relevance for the chemical industry. Here we report the HCl removal performance of ZIF-8 metal organic framework demonstrated via fixed-bed (dynamic) measurements under process conditions. The measurements revealed an HCl removal capacity of 1.02 g/g, outperforming by far all traditional materials and other metal-organic framework previously tested. The ZIF-8, before and after the HCl contact, was characterized via SEM-EDX, XRD, TGA, ATR-FTIR, XPS and Raman spectroscopy. The results showed a dramatic change in textural, structural and chemical properties of ZIF-8 after HCl contact, where the MOF material undergoes a reaction and re-crystalizes into a salt complex. (C) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：20556 / 20560
页数：5
相关论文
共 50 条
  • [41] Metal-organic framework and MXene (ZIF-8:Ti 3 C 2 T x ) based organic and inorganic nanocomposite for bio-synaptic applications
    Abdullah, Mohammedali
    Elango, Indumathi
    Patil, Harshada
    Patil, Pradnya P.
    Aloysius, Deepak
    Gupta, Satyajit
    Selvamani, Muthamizh
    Kim, Deok-kee
    Dongale, Tukaram D.
    Kesavan, Arul Varman
    SURFACES AND INTERFACES, 2024, 51
  • [42] A Flexible Metal-Organic Framework for the Removal of Propyne from Propylene
    Tan, Jian
    Wang, Yi
    Ren, Yongheng
    Li, Jinping
    Chen, Yang
    Li, Libo
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2025, 28 (01)
  • [43] Micropollutants removal from water using microfiltration membrane modified with ZIF-8 metal organic frameworks (MOFs)
    Ragab, D.
    Gomaa, H. G.
    Sabouni, R.
    Salem, M.
    Ren, M.
    Zhu, J.
    CHEMICAL ENGINEERING JOURNAL, 2016, 300 : 273 - 279
  • [44] A high connectivity metal-organic framework with exceptional hydrogen and methane uptake capacities
    Liu, Demin
    Wu, Haohan
    Wang, Shunzhi
    Xie, Zhigang
    Li, Jing
    Lin, Wenbin
    CHEMICAL SCIENCE, 2012, 3 (10) : 3032 - 3037
  • [45] Enrichment of Hydrogen from a Hydrogen/Propylene Gas Mixture Using ZIF-8/Water-Glycol Slurry
    Li, Hai
    Gao, Xueteng
    Jia, Chongzhi
    Chen, Wan
    Liu, Bei
    Yang, Lanying
    Sun, Changyu
    Chen, Guangjin
    ENERGIES, 2018, 11 (07):
  • [46] Properties of Cobalt- and Nickel-Doped Zif-8 Framework Materials and Their Application in Heavy-Metal Removal from Wastewater
    Shen, Bowen
    Wang, Bixuan
    Zhu, Liying
    Jiang, Ling
    NANOMATERIALS, 2020, 10 (09) : 1 - 15
  • [47] Nonideality in the Adsorption of Ethanol/Ethyl Acetate/Water Mixtures On ZIF-8 Metal Organic Framework
    Virdis, Thomas
    Danilov, Valery
    Baron, Gino V.
    Denayer, Joeri F. M.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (20) : 7040 - 7047
  • [48] ZIF-8 Metal Organic Framework for the Conversion of Glucose to Fructose and 5-Hydroxymethyl Furfural
    Oozeerally, Ryan
    Ramkhelawan, Shivendra D. K.
    Burnett, David L.
    Tempelman, Christiaan H. L.
    Degirmenci, Volkan
    CATALYSTS, 2019, 9 (10)
  • [49] Congo red adsorption on metal-organic frameworks, MIL-101 and ZIF-8: kinetics, isotherm and thermodynamic studies
    Yang, Cao
    Yu, Linling
    Chen, Rouxi
    Cheng, Jianhua
    Chen, Yuancai
    Hu, Yongyou
    DESALINATION AND WATER TREATMENT, 2017, 94 : 211 - 221
  • [50] Bioinspired zeolitic imidazolate framework (ZIF-8) magnetic micromotors for highly efficient removal of organic pollutants from water
    Liu, Jun
    Li, Jia
    Wang, Gui
    Yang, Wenning
    Yang, Jie
    Liu, Yong
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 555 : 234 - 244
12345