New pretreatment for elastomers to enhance adhesion

被引：1

作者：

Dahm, RH ^{[1
]}

Brewis, DM ^{[1
]}

Fletcher, IW ^{[1
]}

Mathieson, I ^{[1
]}

机构：

[1] Univ Loughborough, Inst Surface Sci & Technol, Loughborough LE11 3TU, Leics, England

来源：

JOURNAL OF ADHESION | 2005年 / 81卷 / 01期

关键词：

elastomers; solvent-free pretreatments; aqueous Chloramine-T; styrenebutadiene block copolymers (SBS); surface analysis; X-ray photoelectron spectroscopy (XPS); static secondary ion mass spectrometry (SSIMSC);

D O I：

10.1080/00218460590904453

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The effects of various chemical pretreatments on the surface chemistry and adhesion performance of an additive-free styrene-butadiene block copolymer and an additive-free ethylene-propylene elastomer have been studied. Most of the powerful oxidising agents that are effective with hydrocarbon plastics were ineffective in enhancing the adhesion to elastomers despite causing major changes to their surface chemistries. The poor adhesion was attributed to the existence of weak boundary layers. Chlorinated agents were also examined and a new pretreatment for elastomers containing carbon-carbon double bonds has been identified. It was found that a mildly acidified dilute aqueous suspension of Chloramine-T was very effective at enhancing the adhesion performance of styrene butadiene copolymers.

引用

页码：59 / 75

页数：17

共 13 条

[1]

Abbott S, COMMUNICATION

[2]

Bragole R. A., 1974, J ELASTOM PLAST, V6, P213

[3]

BRAGOLE RA, 1974, ADHESIVES AGE APR, P24

[4]

BREMMER DH, 1985, SYNTHETIC REAGENTS, V6, P1

[5] Electrochemical pretreatment of polymers with dilute nitric acid either alone or in the presence of silver ions [J].

Brewis, DM ;

Dahm, RH ;

Mathieson, I .

JOURNAL OF ADHESION, 2000, 72 (3-4) :373-386

[6]

BREWIS DM, 2001, HDB RUBBER BONDING, P12

[7] X-RAY PHOTOELECTRON-SPECTROSCOPY STUDIES OF POLYMER SURFACES .1. CHROMIC ACID ETCHING OF POLYOLEFINS [J].

BRIGGS, D ;

BREWIS, DM ;

KONIECZO, MB .

JOURNAL OF MATERIALS SCIENCE, 1976, 11 (07) :1270-1277

[8]

CHEW A, 1984, ADHESION, V8, P97

[9] Chemical modifications of rubber surfaces: XPS survey of the reactions of trichloroisocyanuric acid at the surfaces of vulcanized elastomers [J].

Lawson, DF ;

Kim, KJ ;

Fritz, TL .

RUBBER CHEMISTRY AND TECHNOLOGY, 1996, 69 (02) :245-252

[10]

MARSH J, 1992, ADV ORG CHEM, P814

← 1 2 →