Structure and bonding in the hydrothermally synthesized copper(I) complex Cu4(μ2-Cl)4(BIPY)2

被引：8

作者：

Moreno, Y

Spodine, E

Vega, A

Saillard, JY

机构：

[1] Univ Chile, Ctr Invest Interdisciplinaria Avanzada Ciencia ma, Fac Ciencias Quim & Farmaceut, Santiago, Chile

[2] Univ Rennes 1, Chim Solide & Inorgan Mol Lab, UMR 6511, CNRS,Inst Chim Rennes, F-35042 Rennes, France

来源：

INORGANICA CHIMICA ACTA | 2003年 / 350卷

关键词：

copper(I); bonding; DFT;

D O I：

10.1016/S0020-1693(02)01494-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound corresponds to a molecular product of the hydrothermal reaction of CuCl2, Zn, and BIPY (BIPY = 2,2'-bipyridine) in the presence of phosphoric acid. The structure of the neutral Complex Cu-4(mu(2)-Cl)(4)(BIPY)(2) determined by means of Xray diffraction consists of molecular units constructed around a Cu-4 parallelogram, with diagonally opposed tetrahedral and linear copper centers. DFT calculations provide a rationalization of the bonding in this molecule. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：651 / 655

页数：5

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