Structure and bonding in the hydrothermally synthesized copper(I) complex Cu4(μ2-Cl)4(BIPY)2

被引：8
|
作者：
Moreno, Y
Spodine, E
Vega, A
Saillard, JY
机构：
[1] Univ Chile, Ctr Invest Interdisciplinaria Avanzada Ciencia ma, Fac Ciencias Quim & Farmaceut, Santiago, Chile
[2] Univ Rennes 1, Chim Solide & Inorgan Mol Lab, UMR 6511, CNRS,Inst Chim Rennes, F-35042 Rennes, France
来源：
INORGANICA CHIMICA ACTA | 2003年 / 350卷
关键词：
copper(I); bonding; DFT;
D O I：
10.1016/S0020-1693(02)01494-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound corresponds to a molecular product of the hydrothermal reaction of CuCl2, Zn, and BIPY (BIPY = 2,2'-bipyridine) in the presence of phosphoric acid. The structure of the neutral Complex Cu-4(mu(2)-Cl)(4)(BIPY)(2) determined by means of Xray diffraction consists of molecular units constructed around a Cu-4 parallelogram, with diagonally opposed tetrahedral and linear copper centers. DFT calculations provide a rationalization of the bonding in this molecule. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：651 / 655
页数：5
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