Readily available new pyridyl alcohols derived from D-glucose as ligands for the enantioselective addition of diethylzinc to aldehydes

被引：15

作者：

Huang, HM ^{[1
]}

Zheng, Z ^{[1
]}

Chen, HL ^{[1
]}

Bai, CM ^{[1
]}

Wang, JW ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(03)00212-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new chiral ligands derived from D-glucose has been synthesized and applied in the enantioselective addition of diethylzinc to aldehydes. Up to 94.1% e.e. was obtained in the ethylation reactions. In contrast to the ligands derived from D-fructose, ligands derived from D-glucose gave the opposite asymmetric induction. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1285 / 1289

页数：5

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