New zeotype borophosphates with chiral tetrahedral topology:: (H)0.5M1.25(H2O)1.5[BP2O8]•H2O (M = Co(II) and Mn(II))

被引：10
|
作者：
Yilmaz, A [1 ]
Yildirim, LT
Bu, X
Kizilyalli, M
Stucky, GD
机构：
[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
[2] Hacettepe Univ, Dept Engn Phys, TR-06800 Ankara, Turkey
[3] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA
[4] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2005年 / 40卷 / 06期
关键词：
borophosphate; molecular sieve; microporous; zeotype; phosphate; boron; manganese; cobalt; crystal structure;
D O I：
10.1002/crat.200410386
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Two new isostructural open-framework zeotype transition metal borophosphate compounds, (H)(0.5)M-1.25(H2O)(1.5)[BP2O8].H2O (M=Co(II) and Mn(II)) were synthesized by mild hydrothermal method. The structure of compounds were characterized by single-crystal X-ray diffraction which have ordered, alternating, vertex-sharing BO4, PO4, and (MO4)OM(H2O)(2) groups with hexagonal, P 6(1) 2 2 (No 178) space group and unit cell parameters for Co a= 9.4960(6) angstrom, c= 15.6230(13) angstrom, for Mn a= 9.6547(12) angstrom, c= 15.791(3) angstrom, Z=1 for both of them. TGA/DTA analysis, IR spectroscopy were used for characterization. Magnetic susceptibility measurements for both of the compound indicate strong antiferromagnetic interaction between metal centers.
引用
收藏
页码：579 / 585
页数：7
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