Highly chemo- and enantioselective arylative cyclization of alkyne-tethered electron-deficient olefins catalyzed by rhodium complexes with chiral dienes

被引：120
|
作者：
Shintani, R [1 ]
Tsurusaki, A [1 ]
Okamoto, K [1 ]
Hayashi, T [1 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 25期
关键词：
asymmetric catalysis; chemoselectivity; cyclization; diene ligands; rhodium;
D O I：
10.1002/anie.200500843
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) A rhodium catalyst promotes the arylative cyclization of alkyne-tethered electron-deficient olefins in the presence of aryl boronic acids. High chemoselectivity was attained uniquely by the use of diene ligands, and high enantioselectivity was successfully realized by employing a C2-symmetric chiral bicyclo[2.2.2]octadiene ligand (see scheme). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：3909 / 3912
页数：4
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