Continuous-flow biodiesel production using slit-channel reactors

被引:31
作者
Kalu, Egwu Eric [1 ]
Chen, Ken S. [2 ]
Gedris, Tom [3 ]
机构
[1] FAMU FSU COE, Chem & Biomed Eng Dept, Tallahassee, FL 32310 USA
[2] Sandia Natl Labs, Albuquerque, NM 87185 USA
[3] Florida State Univ, Chem & Biochem Dept, Tallahassee, FL 32306 USA
关键词
Biodiesel; Reactor; Continuous-flow; Conversion efficiency; Micro-reactors; OIL TRANSESTERIFICATION; VEGETABLE-OIL; MASS-TRANSFER; SOYBEAN OIL; CATALYST; INTENSIFICATION; MICROREACTORS; ALCOHOLYSIS; CONVERSION; BATCH;
D O I
10.1016/j.biortech.2010.12.097
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Slit-channel reactors are reactors whose active surface areas are orders of magnitude higher than those of micro-reactors but have low fabrication costs relative to micro-reactors. We successfully produced biodiesel with different degrees of conversion using homogeneous catalyst in the slit-channel reactor. The reactor performance shows that percent conversion of soybean oil to biodiesel increases with channel depth, as expected, due to more efficient mixing. Shallow slit-channels require short average residence times for complete product conversion. Present results show that the slit-channel reactor provides an improved performance over traditional batch reactors using homogeneous sodium alkoxide catalyst. It is aimed to couple the reactors with solid catalysts in converting soybean oil to biodiesel and implementation method is suggested. The cost advantages resulting from the ease of fabrication of slit-channel reactors over micro-reactors and how these factors relate to the oil conversion efficiency to biodiesel are briefly noted and discussed. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4456 / 4461
页数:6
相关论文
共 30 条
[1]   Enhancement of reaction rates by segmented fluid flow in capillary scale reactors [J].
Ahmed, Batoul ;
Barrow, David ;
Wirth, Thomas .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (09) :1043-1048
[2]  
[Anonymous], 2005, THESIS OREGON STATE
[3]   Continuous-flow preparation of biodiesel using microwave heating [J].
Barnard, T. Michael ;
Leadbeater, Nicholas E. ;
Boucher, Matthew B. ;
Stencel, Lauren M. ;
Wilhite, Benjamin A. .
ENERGY & FUELS, 2007, 21 (03) :1777-1781
[4]   Production of biodiesel using a continuous gas-liquid reactor [J].
Behzadi, Sam ;
Farid, Mohammed M. .
BIORESOURCE TECHNOLOGY, 2009, 100 (02) :683-689
[5]   New heterogeneous process for biodiesel production: A way to improve the quality and the value of the crude glycerin produced by biodiesel plants [J].
Bournay, L ;
Casanave, D ;
Delfort, B ;
Hillion, G ;
Chodorge, JA .
CATALYSIS TODAY, 2005, 106 (1-4) :190-192
[6]   Kinetic Study of Alcoholysis of the Fatty Acids Catalyzed by Tin Chloride(II): An Alternative Catalyst for Biodiesel Production [J].
Cardoso, Abiney L. ;
Neves, Soraia C. G. ;
da Silva, Marcio J. .
ENERGY & FUELS, 2009, 23 (3-4) :1718-1722
[7]   Transesterification of vegetable oil to biodiesel using a heteropolyacid solid catalyst [J].
Chai, Fang ;
Cao, Fenghua ;
Zhai, Fengying ;
Chen, Yang ;
Wang, Xiaohong ;
Su, Zhongmin .
ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (07) :1057-1065
[8]   Kinetics of palm oil transesterification in a batch reactor [J].
Darnoko, D ;
Cheryan, M .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (12) :1263-1267
[9]   Liquid-liquid two-phase flow patterns and mass transfer characteristics in rectangular glass microreactors [J].
Dessimoz, Anne-Laure ;
Cavin, Laurent ;
Renken, Albert ;
Kiwi-Minsker, Lioubov .
CHEMICAL ENGINEERING SCIENCE, 2008, 63 (16) :4035-4044
[10]   Simulation of heterogeneously MgO-catalyzed transesterification for fine-chemical and biodiesel industrial production [J].
Dossin, Tanguy F. ;
Reyniers, Marie-Francoise ;
Berger, Rob J. ;
Marin, Guy B. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 67 (1-2) :136-148