Synthesis, characterization and antimicrobial activity of metal complexes with N,O-bidentate ligand derived from dimedone

被引：5

作者：

Firinci, Rukiye ^{[1
]}

Firinci, Erkan ^{[1
]}

Coban, Esin Poyrazoglu ^{[2
]}

Sevincek, Resul ^{[3
]}

Biyik, Halil ^{[2
]}

Aygun, Muhittin ^{[3
]}

机构：

[1] Adnan Menderes Univ, Fac Arts & Sci, Dept Chem, TR-09100 Aydin, Turkey

[2] Adnan Menderes Univ, Fac Arts & Sci, Dept Biol, TR-09100 Aydin, Turkey

[3] Dokuz Eylul Univ, Dept Phys, Fac Sci, TR-35160 Izmir, Turkey

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2022年 / 141卷

关键词：

Dimedone; N; O-bidentate ligand; Biological activity; X-Ray diffraction; NI(II);

D O I：

10.1016/j.inoche.2022.109509

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One N,O-bidentate dimedone derivatives ligand (1) and its Ni(II), Pd(II), and Cu(II) complexes (2,3,4) have been prepared and structurally characterized by the spectroscopic methods such as FT-IR, NMR, and X-Ray. 1,3, and 4 crystallize in the triclinic crystal system in the space group P-1, 2 crystallizes in the monoclinic crystal system in the space group C2/c. X-Ray diffraction studies showed 1 exists in enamine form, 2-4 have a square planar geometry around metal atoms which are surrounded by two nitrogen and two oxygen atoms from two ligands. Antibacterial properties of 1-4 have been examined against selected bacteria and yeast strains. Also, the minimum inhibitory concentration of 1-4 against these pathogens was compared with the selected antibiotic drugs. The result revealed that all compounds have good activity.

引用

页数：8

共 37 条

[31] 1,2-Diborolanes with strong donor substituents: Synthesis and high antimicrobial activity
Sahin, Yuksel
Coban, Esin Poyrazoglu
Sevincek, Resul
Biyik, Haci Halil
Ozgener, Huseyin
Aygun, Muhittin
[J]. BIOORGANIC CHEMISTRY, 2021, 106
[32] A neutral arene ruthenium(II) complex with a sulfonated N,O-chelating ligand: Synthesis, characterization, in vitro cytotoxicity and antibacterial activity
Selvi, Gizem
Ozdemir, Fethi Ahmet
Aykutoglu, Gurkan
Ozdemir, Namik
Serbetci, Zafer
Cetinkaya, Bekir
Dayan, Osman
[J]. POLYHEDRON, 2020, 176
[33] Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053273314026370, 10.1107/S2053229614024218, 10.1107/S0108767307043930]
[34] Steric, Electronic, and Secondary Effects on the Coordination Chemistry of Ionic Phosphine Ligands and the Catalytic Behavior of Their Metal Complexes
Snelders, Dennis J. M.
van Koten, Gerard
Gebbink, Robertus J. M. Klein
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (01) : 42 - 57
[35] Wikler MA., 2006, CLSI NCCLS, V26, pM7
[36] Structural variation in copper(I) complexes with pyridylmethylamide ligands:: structural analysis with a new four-coordinate geometry index, τ4
Yang, Lei
Powell, Douglas R.
Houser, Robert P.
[J]. DALTON TRANSACTIONS, 2007, (09) : 955 - 964
[37] Effective catalytic disproportionation of aqueous H2O2 with di- and mono-nuclear manganese(II) complexes containing pyridine alcohol ligands
Zienkiewicz, M.
Jablonska-Wawrzycka, A.
Szlachetko, J.
Kayser, Y.
Stadnicka, K.
Sawka-Dobrowolska, W.
Jezierska, J.
Barszcz, B.
Sa, J.
[J]. DALTON TRANSACTIONS, 2014, 43 (23) : 8599 - 8608

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