Synthesis, spectroscopic investigation and molecular structures of [ReBr2(N2COPh)(C3N2H4)(PPh3)2] and [ReBr2(N2COPh)(bpy)(PPh3)]

被引:2
作者
Dziegielewski, JO
Michalik, S
Kruszynski, R
Bartczak, TJ
机构
[1] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland
[2] Tech Univ Lodz, Xray Crystallog Lab, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland
关键词
rhenium; organodiazenido; X-ray structure; electronic structure;
D O I
10.1080/00958970412331336916
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
[ReBr2(eta(2)- N2COPh-N', O)(PPh3)(2)] reacts with bipyridine (bpy) and pyrazole to give [ReBr2(N2COPh)(bpy)(PPh3)] and [ReBr2(N2COPh)(C3N2H4)(PPh3)(2)], respectively. Both complexes have been characterized by IR, electronic and H-1 NMR spectroscopy, magnetic measurements and X-ray structure determination.
引用
收藏
页码:741 / 749
页数:9
相关论文
共 21 条
  • [1] Ardizzoia GA, 1998, EUR J INORG CHEM, P1503
  • [2] BROWN ID, 1994, INORGANIC SOLIDS 3, P405
  • [3] BULKY PYRAZOLE AS LIGANDS IN RHODIUM(I) COMPLEXES - CRYSTAL-STRUCTURE OF CHLORODICARBONYL(3-P-METHOXYPHENYLPYRAZOLE)RHODIUM(I)
    CANO, M
    CAMPO, JA
    HERAS, JV
    LAFUENTE, J
    RIVAS, C
    PINILLA, E
    [J]. POLYHEDRON, 1995, 14 (09) : 1139 - 1147
  • [4] SOME BENZOYLAZO-COMPLEXES OF RHENIUM HALIDES WITH TERTIARY PHOSPHINES, AND RELATED COMPOUNDS
    CHATT, J
    DILWORTH, JR
    LEIGH, GJ
    GUPTA, VD
    [J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (16): : 2631 - &
  • [5] Desiraju G. R., 1999, WEAK HYDROGEN BOND S
  • [6] THE PREPARATION AND SUBSTITUTION CHEMISTRY OF THE CATIONIC BIS(HYDRAZIDO(2-))RHENIUM(VII) COMPLEX [RECL2(NNMEPH)2(PPH3)][BPH4] - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RE(NNMEPH)2(S2CNME2)2][BPH4] AND [REOCL(NNMEPH)(PPH3)2][PF6]2
    DILWORTH, JR
    JOBANPUTRA, P
    PARROTT, SJ
    THOMPSON, RM
    POVEY, DC
    ZUBIETA, JA
    [J]. POLYHEDRON, 1992, 11 (02) : 147 - 155
  • [7] Deboronation of HB(3,5-Me2C3HN2)3- in a reaction with [Re(O)Cl4]-, the X-ray crystal structures of [{Re(O)Cl(3,5-Me2C3HN2H)3}-(μ-O){Re(O)Cl3(3,5-Me2C3HN2H)}] and [{Re(O)Cl2(3,5-Me2C3HN2H)2}(μ-O){Re(O)Cl2(3,5-Me2C3HN2H)2}]
    Hinton, HA
    Chen, HL
    Hamor, TA
    McQuillan, FS
    Jones, CJ
    [J]. INORGANICA CHIMICA ACTA, 1999, 285 (01) : 55 - 59
  • [8] Synthesis and characterization of rhenium(III) and technetium(III) organohydrazide chelate complexes. Reactions of 2-hydrazinopyridine with complexes of rhenium and technetium
    HirschKuchma, M
    Nicholson, T
    Davison, A
    Davis, WM
    Jones, AG
    [J]. INORGANIC CHEMISTRY, 1997, 36 (15) : 3237 - 3241
  • [9] Jeffrey GA, 1994, HYDROGEN BONDING BIO
  • [10] The reactivity of mer-[ReOBr3(bipy)] towards gaseous nitric oxide.: The crystal, molecular and electronic structure of mer-[ReOBr3(bipy)] and[ReBr4(bipy)]
    Machura, B
    Dziegielewski, JO
    Kruszynski, R
    Bartczak, TJ
    Kusz, J
    [J]. POLYHEDRON, 2003, 22 (18) : 2573 - 2580