Stereospecific polymerization of propylene on highly efficient metallocene catalysts

被引：0

作者：

Nedorezova, PM

Tsvetkova, VI

Aladyshev, AM

Savinov, DV

Klyamkina, AN

Optov, VA

Lemenovskii, DA

机构：

[1] Russian Acad Sci, Inst Chem Phys, Moscow 117977, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

POLYMER SCIENCE SERIES A | 2001年 / 43卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The kinetic parameters of the synthesis of iso-, syndio-, hemiisotactic, and stereoblock PP in a liquid propylene using a series of ansa-metallocenes with C-1, C-2, and C-s symmetries activated by methylaluminoxane were studied. For several metallocenes, the effect of hydrogen on the activity and molecular mass characteristics of PP was assessed. The microstructure of the polymer chains, as well as the molecular mass characteristics and thermal, mechanical, and optical properties of the produced polymers, were investigated.

引用

页码：356 / 365

页数：10

共 42 条

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Aladyshev AM, 1997, POLIMERY-W, V42, P595

[2]

[Anonymous], ZIEGLER CATALYSTS

[3]

Bohm L.L., 1999, METALORGANIC CATALYS, P3

[4] STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS [J].