Synthesis and Properties of High Nitrogen-Oxygen Compounds Based on 5,5-Azotetrazolate by Using Microreactors

被引：1

作者：

Deng, Qiulin ^{[1
,2
]}

Du, Jinyan ^{[1
]}

Lei, Qin ^{[1
]}

He, Renxiong ^{[1
]}

Liang, Jianhao ^{[1
]}

Li, Changlin ^{[1
]}

Zhang, Lixiong ^{[3
,4
]}

Jiang, Jinlong ^{[2
]}

机构：

[1] Southwest Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Environm Friendly Energy Mat, 59 Qinglong Rd, Mianyang 621010, Peoples R China

[2] Huaiyin Inst Technol, Jiangsu Prov Key Lab Palygorskite Sci & Appl Tech, 1 Meicheng Rd, Huaian 223003, Peoples R China

[3] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China

[4] Nanjing Tech Univ, Coll Chem & Chem Engn, Nanjing 210009, Jiangsu, Peoples R China

来源：

CHEMICAL ENGINEERING & TECHNOLOGY | 2018年 / 41卷 / 11期

关键词：

Energetic properties; Microreactors; Oxygen-containing salts; SET MODEL CHEMISTRY; SALTS; GENERATION; DESIGN; HEATS;

D O I：

10.1002/ceat.201700694

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A microflow system is easily assembled from a simple T-micromixer, tube microreactor, and several pumps. Herein, the influence of reaction parameters on the microreactor are discussed. The structures of compounds based on 5,5-azotetrazolate were characterized by FTIR, H-1 NMR, and C-13 NMR spectroscopy and elemental analysis. The thermal stabilities of these compounds were investigated by differential scanning calorimetry and thermogravimetric analysis, and the heats of formation and densities were estimated by using the Gaussian 09 program for the Born-Haber energy cycle and Monte-Carlo method, respectively. The detonation pressures and detonation velocities of the anhydrous salts were estimated from the Kamlet-Jacobs equation.

引用

页码：2274 / 2281

页数：8

共 38 条

[1]

[Anonymous], EUR J ORG CHEM

[2]

[Anonymous], 2000, 27 PROC INT PYROTECH

[3]

[Anonymous], ANGEW CHEM INT ED

[4] Crystal structure of bis(hydroxylammonium) 5,5′-azotetrazolate dihydrate, (NH3OH)2(C2N10) • 2H2O [J].

Bentivoglio, Gino ;

Laus, Gerhard ;

Kahlenberg, Volker ;

Nauer, Gerhard ;

Schottenberger, Herwig .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2008, 223 (04) :425-426

[5]

Bucerius K. M., 1993, US Patent, Patent No. 5198046

[6] Improved prediction of heats of formation of energetic materials using quantum mechanical calculations [J].

Byrd, EFC ;

Rice, BM .

JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (03) :1005-1013

[7]

[陈斌 Chen Bin], 2014, [含能材料, Chinese Jouranal of Energetic Materials], V22, P478

[8] Assessment of Gaussian-2 and density functional theories for the computation of enthalpies of formation [J].

Curtiss, LA ;

Raghavachari, K ;

Redfern, PC ;

Pople, JA .

JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (03) :1063-1079

[9] The continuous kilogram-scale process for the synthesis of 2,4,5-trifluorobromobenzene via Gattermann reaction using microreactors [J].

Deng, Qiulin ;

Lei, Qin ;

Shen, Ruwei ;

Chen, Chao ;

Zhang, Lixiong .

CHEMICAL ENGINEERING JOURNAL, 2017, 313 :1577-1582

[10] Bromination of Aromatic Compounds using Bromine in a Microreactor [J].

Deng, Qiulin ;

Shen, Ruwei ;

Ding, Rong ;

Zhang, Lixiong .

CHEMICAL ENGINEERING & TECHNOLOGY, 2016, 39 (08) :1445-1450

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