Biosilica as an efficient heterogeneous catalyst for ipso-hydroxylation of arylboronic acids

被引：51
|
作者：
Mahanta, Abhijit [1 ]
Adhikari, Pooja [1 ]
Bora, Utpal [1 ]
Thakur, Ashim Jyoti [1 ]
机构：
[1] A Cent Univ, Tezpur Univ, Dept Chem Sci, Napaam 784028, Assam, India
来源：
TETRAHEDRON LETTERS | 2015年 / 56卷 / 14期
关键词：
Biosilica; Phenylboronic acid; ipso-Hydroxylation; Hydrogen peroxide; Catalyst; PHENOLS; OXIDATION;
D O I：
10.1016/j.tetlet.2015.02.039
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mild and efficient protocol for the conversion of arylboronic acids to phenol via ipso-hydroxylation has been developed using aqueous hydrogen peroxide as oxidant and biosilica as heterogeneous catalyst. The recyclability of the catalyst is also evaluated and could be reused up to six consecutive cycles without a significant loss in catalytic activity. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1780 / 1783
页数：4
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