Photochemistry of single particles using acoustic levitation coupled with Raman microspectrometry

被引：11

作者：

Tobon, Yeny A. ^{[2
]}

Seng, Samantha ^{[2
]}

Picone, Lorena A. ^{[3
]}

Bava, Yanina B. ^{[3
]}

Juncal, Luciana C. ^{[2
,3
]}

Moreau, Myriam ^{[2
]}

Romano, RosanaM. ^{[3
]}

Barbillat, Jacques ^{[2
]}

Sobanska, Sophie ^{[1
,2
]}

机构：

[1] Inst Sci Mol, CNRS, UMR 5255, 351 Cours Liberat, F-33405 Talence, France

[2] Univ Lille 1 Sci & Technol, CNRS, Lab Spectrochim Infrarouge & Raman, UMR 8516, Bat C5, F-59655 Villeneuve Dascq, France

[3] Univ Nacl La Plata, Dept Quim, Fac Ciencias Exactas, CEQUINOR,CCT,CONICET La Plata, Blvd 120 1465, RA-1900 La Plata, Buenos Aires, Argentina

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 2017年 / 48卷 / 08期

关键词：

photochemistry; acoustic levitation; Raman microspectrometry; single particles; chemical heterogeneity; NITRATE; NITRITE; PEROXYNITRITE; DROPLETS;

D O I：

10.1002/jrs.5181

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The photoreactivity of single particles with atmospheric interest was studied by using an acoustic levitation system coupled to Raman microspectrometry. Both, inorganic and organic single particle phototransformation has been investigated without any surface contact. The Raman microspectrometry has suitably provided the identification, the chemical heterogeneity as well as the formation rates of products. Complex surface limited processes are demonstrated for photolysis of both nitrate-rich and sulfur-rich droplets. Copyright (C) 2017 John Wiley & Sons, Ltd.

引用

页码：1135 / 1137

页数：3

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