Recent Progress in Visible-Light Photoredox-Catalyzed Intermolecular 1,2-Difunctionalization of Double Bonds via an ATRA-Type Mechanism

被引：278

作者：

Courant, Thibaut ^{[1
]}

Masson, Geraldine ^{[1
]}

机构：

[1] Univ Paris Saclay, Univ Paris 11, Inst Chim Subst Nat, CNRS UPR 2301, F-91198 Gif Sur Yvette, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 81卷 / 16期

关键词：

TRANSFER RADICAL-ADDITION; CONCOMITANT INTRODUCTION; COMBINING PHOTOREDOX; PSCHORR REACTION; FACILE SYNTHESIS; DIAZONIUM SALTS; TRIFLUOROMETHYLATION; ALKENES; EFFICIENT; PHOTOCATALYSIS;

D O I：

10.1021/acs.joc.6b01058

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical difunctionalizations of alkenes constitute an efficient method for the construction of complex organic molecules. This synopsis focuses on visible-light catalysis, a recent and very promising technological refinement of this class of transformations. Examples taken from the literature illustrate the use of a variety of (metallic or nonmetallic) systems, which allow us to leverage the energy of readily available visible-light radiation to efficiently create some of the most commonly rooked for types of bonds (C-X, C-O, C-N, and C-C) under mild conditions and starting from unsaturated substrates.

引用

页码：6945 / 6952

页数：8

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